期刊
INORGANIC CHEMISTRY
卷 50, 期 6, 页码 2076-2078出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic102524f
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资金
- National Science Foundation [CHE-0957215]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001011]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0957215] Funding Source: National Science Foundation
Dramatic rate enhancements are observed for the oxidation of phenols, including tyrosine, at indium tin oxide electrodes modified by the addition of the electron-transfer relays [M-II(bpy)(2)(4,4'-(HO)(2)P(O)CH2)(2)bpy)](2+) (M = Ru, Os) with clear evidence for the importance of proton-coupled electron transfer and concerted electron proton transfer.
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