期刊
INORGANIC CHEMISTRY
卷 51, 期 1, 页码 4-6出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic201574m
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-
资金
- Institut Universitaire de France
For the last step of rhodium-catalyzed methanol carbonylation, high-pressure NMR, and kinetic and experimental data supported by density functional theory calculations are consistent with substitution of I- by an AcO- ligand on the [RhI3(COCH3)(CO)(2)](-) species followed by reductive elimination of acetic anhydride, which immediately reacts with water to afford acetic acid.
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