☆ 4.7 Article

Spontaneous Symmetry Breaking during Self-Assembly of a Double Stranded Biphenolate-Based Ti(IV)-Helicate

INORGANIC CHEMISTRY (2010)

期刊

INORGANIC CHEMISTRY

卷 49, 期 14, 页码 6369-6371

出版社

AMER CHEMICAL SOC

DOI: 10.1021/ic100475c

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Chemistry, Inorganic & Nuclear

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CNRS
French government

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Reagent

摘要

A binuclear Ti(IV)-based helicate synthesized from a symmetric tetrahydroxyheptaphenylene strand was self-assembled in solution and shown to undergo a spontaneous head-to-tail differentiation according to single-crystal X-ray diffraction.

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