期刊
INORGANIC CHEMISTRY
卷 49, 期 16, 页码 7223-7225出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic100686m
关键词
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资金
- National Center for Research Resources [G12RR013459]
- National Science Foundation [CHE-0821357, CHE-0130835]
- University of Oklahoma
A macrocyclic dinuclear copper complex, [Cu-2(II)(1)Br-3(H2O)]Br, has been synthesized and characterized by X-ray crystallography, in which the macrocycle is folded to form a bowl-shaped cavity. The sensing ability of the receptor has been studied for halides by UV-vis spectroscopy in water acetonitrile (1:3, v/v) and water. The results indicate that the new receptor exhibits a strong affinity and selectivity for iodide.
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