期刊
INORGANIC CHEMISTRY
卷 49, 期 8, 页码 3679-3681出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic902450c
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资金
- National Natural Science Foundation of China [20671082, 20971110, J0830412]
- New Century Educational Talents Plan [NCET-07-0765]
- Outstanding Talents Foundation by the Henan province
An unprecedented high-nuclearity metallamacrocycle-based 3D silver framework with formula {[Ag-2(C25H27N6O)(2)](CH3OH)(H2O)(0.17)}(n) (1), built on the basis of dodecanuclear silver building blocks, has been synthesized and characterized, and it shows strong phosphorescence emission at 10 K, which is a consequence of the presence of intersystem crossing from singlet to triplet caused by the heavy-atom effect of silver ions.
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