期刊
INORGANIC CHEMISTRY
卷 49, 期 22, 页码 10214-10216出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic101321u
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资金
- Louth & Roscommon Co. Councils
- Nanoned
- NWO
Time-resolved infrared spectroscopy was used to probe the photochemistry of three (mu(2)-alkyne)Co-2(CO)(6) complexes. The data indicate the formation of a triplet diradical species, with lifetimes in the range 38-71 ps. Theoretical calculations support these experimental findings. No evidence for the CO loss species, (mu(2)-alkyne)Co-2(CO)(5), was observed, and this is rationalized by the low quantum yield for this process at the excitation wavelengths used.
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