Article
Chemistry, Multidisciplinary
Jia-Yuan Zhao, Ning Ren, Ying-Ying Zhang, Kun Tang, Jian-Jun Zhang
Summary: This article presents a series of newly synthesized complexes and their characterization studies. Single crystal data revealed that these complexes are binuclear and possess different crystal structures. The thermal decomposition mechanism of these complexes was investigated using TG/DSC-FTIR technology.
FRONTIERS IN CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Nikita Y. Shmelev, Tesfu H. Okubazghi, Pavel A. Abramov, Vladislav Y. Komarov, Mariana I. Rakhmanova, Alexander S. Novikov, Artem L. Gushchin
Summary: Treating [(PPh3)AuCl] complex with silver triflate in dichloromethane leads to synthesis of dinuclear gold(I) complexes with high yields. Crystal structures show linear gold ions with twisted bipyridine ligands allowing aurophilic interactions. Photoluminescence in solid state with different emission colors and phosphorescent lifetimes is observed when excited at 300 nm.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Physical
Ismail Yilmaz, Nursel Acar-Selcuki, Simon J. Coles, Fatih Pekdemir, Abdurrahman Sengul
Summary: A new unsymmetrically substituted 2,2'-bipyridine ligand (L) was isolated and characterized in this study, along with its coordination compounds with platinum(II) and silver(I). The structures and properties of the complexes were studied using spectroscopic and X-ray techniques, and DFT calculations were performed to compare with experimental results.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Inorganic & Nuclear
Nataliya Plyuta, Thomas Cauchy, Miguel Julve, Narcis Avarvari
Summary: Two new luminescent ligands were successfully synthesized through Suzuki coupling reactions. DFT and TD-DFT calculations were performed to analyze the UV-visible and emission bands. The experimental results revealed the coordination modes and structural characteristics of the ligands with metal ions. The products showed strong luminescence properties in solution and the solid state, and magnetic studies indicated small antiferromagnetic interactions in some of the compounds.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Samuel Lauzon, Thierry Ollevier
Summary: By designing a novel chiral ligand, high levels of stereoselectivity can be achieved in synthetic reactions. The unique properties of the new ligand can enhance both reaction yields and enantioselectivities.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Andre Ferrarini, Rafael Natan Soek, Rafaella Rebecchi Rios, Francielli Sousa Santana, Renan Borsoi Campos, Roberto Santana da Silva, Fabio Souza Nunes
Summary: Two novel ruthenium-nitrosyl complexes were synthesized and characterized. RuLANO can release chloride ions and dissociate NO upon irradiation, while Ru3LBNO is photo-inactive in a specific wavelength range. These results are consistent with calculations and electrochemical responses.
INORGANICA CHIMICA ACTA
(2022)
Article
Optics
Anuj Dalal, Kapeesha Nehra, Anjli Hooda, Devender Singh, Rajender Singh Malik, Sumit Kumar
Summary: This paper highlights the synthesis of fluorescent derivatives of 2,2'-bipyridine, showcasing their applications in electroluminescent devices. The compounds were characterized using various spectroscopic techniques and photophysical properties were identified through photoluminescence spectra. Additionally, the compounds' electrochemical behavior was studied and their kinetic stability and chemical inertness were confirmed through optical band gap data analysis.
Article
Chemistry, Applied
Yi Liu, Wenjing Zhu, Xiao Yu, Hongyan Liu, Zenghui Zhang, Mei Zhang, Jinbo Zhao, Yacong Wang, Chengcai Xia
Summary: A method for synthesizing dihydropyrazoles has been developed, featuring mild reaction conditions and good functional group tolerance.
ADVANCED SYNTHESIS & CATALYSIS
(2022)
Article
Thermodynamics
Dan-Dan Du, Ning Ren, Jian-Jun Zhang
Summary: Two novel isostructural lanthanide complexes were synthesized using 2-fluorobenzoic acid and 5,5'-dimethy-2,2'-bipyridine, characterized by IR, elemental analysis, and single-crystal X-ray diffraction, showing specific crystal structure and thermal behavior.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2022)
Article
Chemistry, Medicinal
Oscar Mammoliti, Adeline Palisse, Caroline Joannesse, Sandy El Bkassiny, Brigitte Allart, Alex Jaunet, Christel Menet, Beatrice Coornaert, Kathleen Sonck, Inge Duys, Philippe Clement-Lacroix, Line Oste, Monica Borgonovi, Emanuelle Wakselman, Thierry Christophe, Nicolas Houvenaghel, Mia Jans, Bertrand Heckmann, Laurent Saniere, Reginald Brys
Summary: Studies suggest that blocking S1P2 receptor signaling could be effective for treating idiopathic pulmonary fibrosis, with only a few antagonists disclosed so far. A chemical enablement strategy led to the discovery of a pyridine series with good antagonist activity, and further optimization identified a compound with potent activity in a phenotypic IL8 release assay and bleomycin-induced model of pulmonary fibrosis.
JOURNAL OF MEDICINAL CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Guangfu Li, Shaoqing Shi, Ying Gao, Dongxia Zhu, Zhongmin Su
Summary: Two new near-infrared emissive iridium complexes were designed and synthesized in this study, both showing mechanochromic luminescent behavior attributed to physical phase transformations from amorphization to crystallization.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2021)
Article
Chemistry, Applied
Jun Ni, Zhongcui Guo, Qiong Zhu, Shuqin Liu, Jianjun Zhang
Summary: This article reports the synthesis and characterization of three novel square-planar platinum(II) complexes. These complexes exhibit sensitive response to volatile organic compound (VOC) vapors and show potential application prospects in visual detection.
Article
Chemistry, Multidisciplinary
Wided Hagui, Marie Cordier, Julien Boixel, Jean-Francois Soule
Summary: A new method for photoredox-mediated C-H bond alkylation of 6-aryl-2,2'-bipyridines with N-(acyloxy)phthalimides has been reported, showing excellent functional group tolerance, including chiral aliphatic groups. The influence of the incorporated C6'-alkyl group on the photophysical properties of the corresponding (N^C^N) cyclometalated Pt(u) complexes, including chiroptical properties, has been described.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Zekeriya Dogan, Nursel Acar Selcuki, Simon J. Coles, Abdurrahman Sengul
Summary: This study reports the synthesis and characterization of a coordination compound formed by platinum ions with a sterically hindered N4-donor ligand, exhibiting a diamond-shaped structure. The molecular units in the lattice form dimers in a head-to-tail fashion through hydrogen bonding, with the solvent molecule playing a key role in stabilizing the structure through hydrogen bonding. The DFT and TD-DFT results are consistent with experimental observations, showing stable hydrogen bond interactions between the monomers.
INORGANICA CHIMICA ACTA
(2022)
Article
Crystallography
Nian-Juan Pan, Chang Yan, Qiang Fei, Wen-Neng Wu
Summary: This is a compound of C17H18F6N6O, belonging to the monoclinic crystal system with space group P2(1)/n (no. 14). The lattice parameters are a=9.9491(11) Å, b=18.1523(17) Å, c=11.7703(15) Å, β=113.473(14)°, and the volume is 1949.8(4) ų. There are 4 molecules in the unit cell. The R-factor (R-gt(F)) is 0.0606 and the weighted R-factor (wR(ref)(F-2)) is 0.1876. The temperature is 169.99(10) K.
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES
(2023)
Article
Chemistry, Inorganic & Nuclear
Jie Yan, Qin Xue, Hui Yang, Shek-Man Yiu, Ye-Xin Zhang, Guohua Xie, Yun Chi
Summary: Six novel homoleptic Ir(III) complexes with imidazo-[4,5-b]pyrazin-2-ylidene chelates have been successfully designed and synthesized. These complexes exhibit narrowband blue and broadened green emission in degassed toluene solution, with high photoluminescent quantum yields. The tert-butylphenyl cyclometalate is found to be more electron donating than the N-phenyl cyclometalate, resulting in a red-shifted emission. Furthermore, OLED and hyper-OLED devices utilizing these complexes as dopants or sensitizers have demonstrated high external quantum efficiencies and narrowband emissions.
INORGANIC CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Xiaomei Peng, Chia-Hsiu Yeh, Sheng Fu Wang, Jie Yan, Shifeng Gan, Shi-Jian Su, Xiuwen Zhou, Ye-Xin Zhang, Yun Chi
Summary: Near-infrared emitting Os(II) complexes with improved emission properties and increased radiative lifetime are successfully developed by introducing 4-(trifluoromethyl)phenyl on pyrazine. The influence of C-H(D) stretching vibrations on non-radiative transition processes is confirmed, leading to the fabrication of efficient NIR organic light-emitting diodes.
ADVANCED OPTICAL MATERIALS
(2022)
Review
Chemistry, Multidisciplinary
Yu-Chen Wei, Kai-Hua Kuo, Yun Chi, Pi-Tai Chou
Summary: Designing bright and efficient near-infrared (NIR) emitters has become a hot research topic in the fields of biological imaging, medical therapy, optical communication, and night-vision devices. Two complementary approaches, exciton delocalization and molecular deuteration, have been proposed to suppress nonradiative internal conversion rates and increase the efficiency of NIR emission. This concept has been experimentally verified using square-planar Pt(II) complexes. The results show high NIR emission efficiency and photoluminescent quantum yield.
ACCOUNTS OF CHEMICAL RESEARCH
(2023)
Article
Nanoscience & Nanotechnology
Jie Yan, Sheng Fu Wang, Chao-Hsien Hsu, Emily Hsue-Chi Shi, Chi-Chi Wu, Pi-Tai Chou, Shek-Man Yiu, Yun Chi, Caifa You, I-Che Peng, Wen-Yi Hung
Summary: In this study, we synthesized different blue emitting homoleptic iridium(III) phosphors with specific cyclometalates. These iridium complexes displayed intense phosphorescence in the solution state and were able to transfer energy to multiresonance thermally activated delayed fluorescence (MR-TADF) terminal emitters via Fo''rster resonance energy transfer (FRET). OLEDs using these phosphors achieved true blue, narrow bandwidth emission with high efficiency. The research also analyzed the kinetic parameters involved in energy transfer processes and proposed ways to improve efficiency roll-off.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Yu-Chen Wei, Bo-Han Chen, Ren-Siang Ye, Hsing-Wei Huang, Jia-Xuan Su, Chao-Yang Lin, Justin Hodgkiss, Lian-Yan Hsu, Yun Chi, Kai Chen, Chih-Hsuan Lu, Shang-Da Yang, Pi-Tai Chou
Summary: Based on transient absorption spectroscopy and transient grating photoluminescence spectroscopy, this study reveals the collective out-of-plane motions of the aggregated Pt-II complex 4H in excited states, which facilitate the excited-state deactivation and enhance the near-infrared emission efficiency.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Biochemistry & Molecular Biology
Junghwa Lee, Pyoungsik Shin, Pi-Tai Chou, Taiha Joo
Summary: The excited state intramolecular proton transfer (ESIPT) dynamics of o-hydroxy analogs of the GFP chromophore were investigated using time-resolved spectroscopies and theoretical calculations. These compounds are an ideal system for studying the influence of electronic properties on the energetics and dynamics of ESIPT, as well as for applications in photonics. Through high-resolution time-resolved fluorescence and quantum chemical methods, the ultrafast ESIPT process was observed in 30 fs. While the ESIPT rates were not affected by the electronic properties of the substituents, the energetics, structures, dynamics following ESIPT, and possibly the product species were found to be distinct. The results suggest that fine tuning the electronic properties of these compounds can modify the molecular dynamics of ESIPT and subsequent structural relaxation to achieve brighter emitters with broad tuning capabilities.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Nanoscience & Nanotechnology
Jin-Tin Lin, Chia-Sheng Huang, Cheng Ming Hui, Yu-Hong Liang, Luke The, Fang-Hsien Lu, Yun Chi, Sheng-Fu Wang, K. R. Justin Thomas, Jwo-Huei Jou
Summary: Nanoparticles can enhance the performance of optoelectronic devices, but their limited absorption bandwidth at around 520 nm restricts their effectiveness in the red region. However, this study demonstrates that a single nanoparticle based on nonprecious copper can significantly enhance the efficiency of LEDs of all colors, with an unprecedented wide absorption band.
ACS APPLIED NANO MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Jie Yan, Zi-Qi Feng, Yixin Wu, Dong-Ying Zhou, Shek-Man Yiu, Chin-Yiu Chan, Yi Pan, Kai Chung Lau, Liang-Sheng Liao, Yun Chi
Summary: Efficient blue phosphors for OLEDs remain challenging. Researchers have synthesized a series of Ir(III) complexes and studied their structures and photophysical properties to overcome this challenge. Some of the emitters can undergo interconversion without decomposition in a specific solvent. The synthesized Ir(III) complexes exhibit good luminescence properties and show potential for making blue OLEDs.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Jie Yan, Min Song, Dong-Ying Zhou, Shek-Man Yiu, Liang-Sheng Liao, Yun Chi, Mo Xie
Summary: Homoleptic charge-neutral Ir(III) metal complexes with tridentate chelates composed of pyrazole-pyridine-pyrazolefragments were synthesized, and the substituents on the chelate played a significant role in tuning their photophysical and electrochemical properties. By introducing CF3 substituents at specific positions, the phosphorescence color of the complexes could be adjusted from green to orange with improved emission quantum yield. The newly synthesized Ir(III) complexes showed high thermal stability and were applied as dopant emitters in OLEDs, exhibiting high external quantum efficiency and current efficiency.
Article
Multidisciplinary Sciences
Jie Yan, Dong-Ying Zhou, Liang-Sheng Liao, Martin Kuhn, Xiuwen Zhou, Shek-Man Yiu, Yun Chi
Summary: In this study, four Ir(III) metal complexes were designed to achieve efficient blue emission through efficient energy transfer. The complexes also underwent isomerization in the presence of catalysts, allowing for mass production. The resulting hyper-OLED displayed true-blue color and high external quantum efficiency, paving the way for innovative blue OLED technology.
NATURE COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
Jie Yan, Min Song, Dong-Ying Zhou, Guowei Ni, Muhua Gu, Shek-Man Yiu, Xiuwen Zhou, Liang-Sheng Liao, Yun Chi
Summary: Efficient saturated red and near-infrared emissive bis-tridentate Ir(III) complexes have been synthesized for the development of organic light-emitting diodes (OLEDs). The resulting OLED devices demonstrate high external quantum efficiencies and emission peak wavelengths.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Jie Yan, Yixin Wu, I-Che Peng, Yi Pan, Shek-Man Yiu, Ken-Tsung Wong, Wen-Yi Hung, Yun Chi, Kai-Chung Lau
Summary: In this study, three Ir(iii) based carbene complexes were synthesized and characterized. These complexes exhibited sky-blue emission and high photoluminescent quantum yields. One of the complexes showed high efficiency and external quantum efficiency in blue OLED devices.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Ze-Lin Zhu, Jie Yan, Li-Wen Fu, Chen Cao, Ji-Hua Tan, Sheng-Fu Wang, Yun Chi, Chun-Sing Lee
Summary: By modifying Pt(ii) dicarbene pincer complexes, the effect of aromatic substituents on excimer formation was studied. IPrtBuPt showed high stability and ultrahigh luminous efficiency, maintaining blue emission at doping concentrations of up to 20%. Furthermore, the emission of IPrtBuPt significantly overlapped with the absorption of nu-DABNA, achieving high EQEs, narrow FWHM, and specific CIE coordinates in a hyper-OLED structure.
MATERIALS CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Inorganic & Nuclear
Guowei Ni, Jie Yan, Yixin Wu, Fan Zhou, Pi-Tai Chou, Yun Chi
Summary: Third-row transition-metal complexes are crucial in the production of light-emitting layers for OLED technology. It is essential to extend their emission wavelengths to true-blue and near-infrared regions to enhance the performance and enable new applications. This chemistry frontier article elaborates on using transition metals like iridium and platinum and carefully designed chelates to assemble advanced emitters.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Nanoscience & Nanotechnology
Eun Hae Cho, Hye-Ryung Choi, Yongjin Park, So Yeong Jeong, Young Jin Song, Yong Ha Hwang, Junwoo Lee, Yun Chi, Sheng-Fu Wang, Yongmin Jeon, Chang-Hun Huh, Kyung Cheol Choi
Summary: This study focuses on wearable and wavelength-tunable near-infrared organic light-emitting diodes (NIR OLEDs) that use a silver electrode instead of the traditional indium tin oxide (ITO) electrode. The NIR OLEDs show stable operation and wavelength tuning capabilities, and have a promoting effect on cell proliferation under NIR light irradiation, indicating their potential for efficacious phototherapy.
ACS APPLIED MATERIALS & INTERFACES
(2023)