期刊
INORGANIC CHEMISTRY
卷 48, 期 21, 页码 10146-10150出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic901085p
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资金
- NSFC [20871034]
- GXSFC [0832001Z]
- University of the Ministry of Education China [NCET-07-217]
- New Century of Guangxi [2006201]
- Fok Ying Tung Education Foundation [111014]
The first structurally authenticated example of coordinated polymer featuring homometallic pillared-trilayer structure, [Co-3(ina)(2)(PiCo)(2)(H2O)(2)](n) (1), was built from mixed pyridyl-type monocarboxylates, isonicotinate (ina) and 3-hydroxypicolinate (pico), containing Kagome-type [Co-3(Pico)(2)(H2O)(2)](n)(2n+) trilayers. The magnetic phase diagram of 1 shows a metamagnetic transition below 3.2 K, arising from the competing interactions between the antiferromagnetic intralayer couplings in different amplitudes with obviously noncompensated moments versus weak AF interlayer coupling.
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