Article
Chemistry, Inorganic & Nuclear
Sibo Wang, Bo Sun, Zhongmin Su, Guohui Hong, Xiao Li, Yanling Liu, Qingqing Pan, Jing Sun
Summary: In this study, five isostructural lanthanide metal-organic frameworks were synthesized and shown to have excellent processability and multifunctional luminescent characteristics. One of the compounds also demonstrated excellent temperature sensing performance. Additionally, two of the compounds were found to be fluorescent sensors for detecting multiple substances.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Inorganic & Nuclear
Xu Zhang, Dongyan Liu, Jiahui Yu, Xin Li, Hanwen Zheng, Yanan Zhou, Cuiying Huang, Yanyu Zhu, Chengqi Jiao, Zhengang Sun
Summary: By selecting a bisphosphonic ligand H4L and a coligand oxalate, three isostructural lanthanide metal-organic frameworks (Ln-MOFs) with a 2D layer structure were synthesized. By tuning the molar ratio of different lanthanide ions, doped Ln-MOFs with variable luminescent colors were obtained, which can be potentially used in anti-counterfeiting applications. Moreover, one of the Ln-MOFs (3) showed good thermal, water, and pH stabilities, and served as a selective and reusable luminescent sensor for sulfamethazine (SMZ).
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Xu Zhang, Xin Li, Tianyang Ding, Jiahui Yu, Chengqi Jiao, Ye Hu, Yanan Zhou, Yanyu Zhu, Zhengang Sun, Hanwen Zheng
Summary: By introducing Tb3+ ions, researchers have successfully developed a Zn-based coordination polymer that can be used as a highly sensitive and selective luminescent probe for the UV filter benzophenone (BP), enabling naked-eye detection. This work provides a novel strategy for the construction of ratiometric luminescent probes for BP-type UVFs through coordinated postsynthetic modification.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Ting Pan, Peng Wu, Weina Zhang, Yu Shen, Fengwei Huo
Summary: Sensitive sensing of nitroaromatic compounds is achieved using luminescent lanthanum-tricarboxytriphenylamine nanosheets, which exhibit multiple responsive behaviors.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Yunseung Kuk, Kang Min Ok
Summary: Six enantiomorphic lanthanide-organic coordination polymers have been grown through solvothermal reactions, showing chiral structures directed by chiral TBA ligands and possessing noncentrosymmetric polar space group structures. These chiral coordination polymers not only absorb circularly polarized light, but also exhibit second-harmonic generation signals from the macroscopic NCS structures.
Review
Chemistry, Inorganic & Nuclear
Danyu Lv, Wenqian Nong, Yongguang Guan
Summary: Edible ligand-metal-organic frameworks (EL-MOFs) have great potential in various practical applications with advantages such as high porosity, large specific surface area, flexible pore structure, nontoxicity, biocompatibility, and environmental friendliness. The synthesis, physical and chemical properties, biocompatibility, and potential applications of EL-MOFs have been comprehensively analyzed and discussed. Opportunities and challenges of EL-MOFs in the future were also prospectively discussed.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Inorganic & Nuclear
Youenn Pointel, Carole Daiguebonne, Yan Suffren, Francois Le Natur, Stephane Freslon, Guillaume Calvez, Kevin Bernot, David Jacob, Olivier Guillou
Summary: Luminescent and color-tunable stable colloidal suspensions of molecular alloys were reported, produced via a green synthetic route. These suspensions have high luminescence intensity and wide color range, making them suitable for tagging technical liquids. They can also be used in ink-jet printers for luminescent anti-counterfeiting tagging.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Inorganic & Nuclear
Zhangjian Li, Qin Wang, Kuangli Yu, Wenlu Cui, Yabing He, Banglin Chen, Dian Zhao
Summary: In this study, a multimodal luminescent ratiometric thermometer based on a single-lanthanide MOF was developed. It has both the characteristic luminescence of Dy3+ and ligand fluorescence, allowing accurate temperature determination through different modes. This thermometer shows promising thermometric performance and can broaden the application scope of ratiometric luminescent thermometers.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Yating Wan, Jie Wang, Hua Shu, Benyuan Cheng, Zhiyu He, Peipei Wang, Tifeng Xia
Summary: This study synthesized a series of lanthanide metal-organic frameworks with a specific ligand and investigated the interference of the SHG signal. It was found that Ln-MOFs with noncentrosymmetric C2 space group exhibit SHG property, depending on the type of metal atoms, pumping wavelength, and crystal size. The systematic study provides interesting results and enriches the research scope of nonlinear optics and materials science.
INORGANIC CHEMISTRY
(2021)
Article
Multidisciplinary Sciences
Li-Hao Xu, Shen-Hui Li, Heng Mao, Yan Li, Ao-Shuai Zhang, Sen Wang, Wei-Min Liu, Jing Lv, Tao Wang, Wei-Wei Cai, Le Sang, Wen-Wen Xie, Chan Pei, Zheng-Zheng Li, Ying-Nan Feng, Zhi-Ping Zhao
Summary: This study presents a strategy to create highly flexible metal-organic framework nanosheet membranes for alcohol-water separation. The membranes exhibited ultrafast transport channels and achieved high flux and separation performance.
Article
Chemistry, Multidisciplinary
Xiurong Zhang, Weidong Fan, Weifeng Jiang, Yue Li, Yutong Wang, Mingyue Fu, Daofeng Sun
Summary: Regulating the structure of metal-organic frameworks (MOFs) through adjusting ligands can enhance interaction with special molecules/ions, leading to significant applications in selective adsorption. The designed tricarboxylic ligands showed high adsorption capacity for guest molecules, demonstrating the importance of precise ligand modification in improving the performance of MOFs.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Inorganic & Nuclear
Gen Li, Shuai-Liang Yang, Wan-Shan Liu, Meng-Yue Guo, Xiao-Yan Liu, Ran Bu, En-Qing Gao
Summary: A novel Eu(iii) metal-organic framework with 3-fold interpenetration exhibits multi-responsive behaviors such as photochromism, photoluminescence, and sensing of ammonia and O-2. Charge transfer within the framework and host-guest electron transfer lead to fluorescence quenching, color change, and size-selective response to ammonia and amines.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Multidisciplinary
Arijit Halder, Ryan A. Klein, Sarah Shulda, Gavin A. McCarver, Philip A. Parilla, Hiroyasu Furukawa, Craig M. Brown, C. Michael McGuirk
Summary: Step-shaped adsorption-desorption of gaseous payloads by flexible metal-organic frameworks can facilitate the delivery of large usable capacities with reduced energetic penalties. The multivariate linker approach is a powerful tool for tuning the phase change behavior of flexible frameworks. In this work, a multivariate framework was developed with a considerably reduced threshold pressure and desirable adsorption-desorption profile for efficient storage and delivery of weakly physisorbing species.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Inorganic & Nuclear
Yu-Hsiang Liu, Tsung-Te Liao, Shu-Yu Lin, Shih-Ying Zhong, Tsun-Ren Chen, Jhy-Der Chen
Summary: Four Cd(II) and Zn(II) coordination polymers were constructed and structurally characterized. They showed different structural topologies, indicating the metal and ligand effects on structural diversity. Additionally, the luminescent properties of the coordination polymers were evaluated, and one of them exhibited good sensitivity and integrity for the detection of Fe3+ ion.
INORGANICA CHIMICA ACTA
(2023)
Article
Engineering, Environmental
Fangna Dai, Xiaokang Wang, Shuanghao Zheng, Jianpeng Sun, Zhaodi Huang, Ben Xu, Lili Fan, Rongming Wang, Daofeng Sun, Zhong-Shuai Wu
Summary: In this study, a new 3D bulk MOF and new 2D ultrathin MOF nanosheets were successfully synthesized and utilized as high-capacitance microelectrode materials for sophisticated all-solid-state MSC devices. The MSCs based on the MOF nanosheets exhibited higher performance than those based on MOF bulks, showing promising potential for microscale energy storage applications.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Jianjian Yang, Changsong Xie, Qianqian Yang, Shuang Wang, Yun Gao, Jiahui Ji, Zecheng Du, Zixi Kang, Rongming Wang, Daofeng Sun
Summary: By coating different proportions of PANa on the COF surface, the proton conductivity of COFs can be greatly improved, resulting in significantly higher proton conductivity. This work not only develops a new method, but also demonstrates the crucial role of ordered channels in constructing effective proton conduction pathways.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Organic
Qiuling Wan, Luoting Xin, Jian Zhang, Xueliang Huang
Summary: This study describes a gold-catalysed cycloisomerization of 1,5-diynes, providing a selective access to 1,3,4-trisubstituted pyrroles. The cationic gold catalyst activates the ynamide moiety, initiating the cycloisomerization to produce the pyrrole core. Water acts as an external nucleophile to trap the vinyl cationic species, leading to the formation of 1,3,4-trisubstituted pyrroles with high selectivity.
ORGANIC & BIOMOLECULAR CHEMISTRY
(2022)
Article
Forestry
Mingfu Li, Yi Liu, Chunlin Chen, Jian Zhang, Shuangfei Wang, Douyong Min
Summary: In this study, hot water and green liquor pretreatments were performed on Eucalyptus wood. The cellulase adsorption behavior on isolated lignins and model compounds was investigated using QCM-D and AFM. The results showed that hot water pretreated lignin adsorbed more cellulase compared to green liquor pretreated lignin and protolignin. The interaction force between lignin and cellulase followed the order of hot water pretreated lignin > green liquor pretreated lignin > protolignin. Additionally, the presence of a ketone group in the monomeric lignin model promoted higher cellulase adsorption compared to the hydroxyl group or aldehyde group.
WOOD SCIENCE AND TECHNOLOGY
(2022)
Review
Chemistry, Multidisciplinary
Lei Zhang, Xi Fan, Xiaofeng Yi, Xin Lin, Jian Zhang
Summary: The article introduces a controllable method for preparing titanium-oxo clusters, and significant progress has been made in TOC synthesis using the coordination-delayed-hydrolysis strategy, which can adjust the structures of TOCs and optimize their properties.
ACCOUNTS OF CHEMICAL RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Jiajin Xia, Baolong Zhu, Qiuling Wan, Yinghua Yu, Shenlin Huang, Jian Zhang, Xueliang Huang
Summary: Transition metal-catalyzed divergent synthesis through alternation of the catalyst is demonstrated, providing an operationally simple way to access different valuable products from the same reactants. A gold-catalyzed cascade reaction of conjugated diynamides with allylic alcohols is described, giving selectively substituted allenes and furans by varying the catalysts. Mechanistic studies reveal a [3,3]-sigmatropic rearrangement and an intramolecular Himbert arene/allene Diels-Alder cycloaddition as additional reaction sequences to access dearomatized products with bicyclo[2,2,2]octadiene core.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Materials Science, Multidisciplinary
Zhi-Run Wang, Jun-Qiang Chen, Qiao-Hong Li, Hai-Xia Zhang, Jian Zhang
Summary: This study reports 2D lead-MOFs that generate white light through the combined effect of free excitons and self-trapped excitons. The synthesized BIF-142-Cl exhibits outstanding white-light emission with color coordinates close to pure white light, excellent color rendering index, and gentle correlation color temperature. Additionally, the emission can be adjusted from blue to white light by changing the excitation wavelength. This synthetic strategy not only offers potential for solid-state lighting materials but also expands possibilities in anticounterfeiting, display media, and information identification fields.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Mengfei Li, QianQian Yang, Lili Fan, Xiaojie Dai, Zixi Kang, Rongming Wang, Daofeng Sun
Summary: Researchers have developed alternative electrocatalysts with high stability for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). The electrocatalyst, composed of hollow CoOx nanoparticles embedded in carbon nanofibers, showed excellent long-term stability and promising performance in reversible Zn-air batteries. The remarkable electrocatalytic performance is attributed to the optimized adsorption of *OOH intermediate and reduced free energy of the potential-limiting step.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Yi-Hong Xiao, Zhi-Zhou Ma, Xue-Xian Yang, Dong-Sheng Li, Zhi-Gang Gu, Jian Zhang
Summary: This study demonstrates the synthesis of ordered chiral carbon nanodot arrays in a porous material, which enables efficient circularly polarized luminescence. By confining chiral amino acids in the porous material and carbonizing them into chiral carbon nanodots, the transfer of chirality on the excited state is achieved, resulting in strong CPL performance.
Article
Chemistry, Multidisciplinary
Ping Shao, Yu-Mei Wan, Luocai Yi, Shumei Chen, Hai-Xia Zhang, Jian Zhang
Summary: In this study, a Cu@BIF-144(Zn) composite is synthesized and shown to exhibit a synergistic effect in CO2RR, enhancing selectivity and activity for the production of multi-electron-transfer products.
Article
Materials Science, Multidisciplinary
Dong-Fei Lu, Shangda Li, Ming-Xue Guan, Yu-Peng Han, Yayong Sun, Xin Wu, Fei Wang, Jian Zhang
Summary: In this study, the first visible-light-active titanium sulfonate metal-organic framework (FIR-138) with 2-fold interpenetrated srs topology was successfully synthesized. FIR-138 exhibited good stability and excellent visible-light absorption performance, and demonstrated outstanding visible-light photocatalytic performance in organic reactions.
ACS MATERIALS LETTERS
(2023)
Article
Chemistry, Inorganic & Nuclear
Jianjian Yang, Zhihui Kong, Xinyu Li, Qinglei Guo, Zhen Wang, Zixi Kang, Rongming Wang, Daofeng Sun
Summary: The long-term stability of proton conductors is important for evaluating materials. This paper synthesized a sulfonated covalent organic framework with intrinsic proton conductivity, and further improved the proton conductivity by coating a superabsorbent polymer. The modified composite exhibited ultrahigh proton conductivity and long-term durability.
Article
Materials Science, Multidisciplinary
Qianqian Yang, Xinyu Li, Changsong Xie, Zhen Wang, Zhihui Kong, Jianjian Yang, Zixi Kang, Rongming Wang, Daofeng Sun
Summary: In this study, a sulfonate-containing hydrogen bonded organic framework (HOF) was synthesized and its stability was improved by crosslinking its crystal particles through an in situ reaction. The resulting HOF-based composite showed excellent stability in various solvents and strong acid/base solutions. Furthermore, the introduction of NH4+ ions significantly enhanced the proton conductivity of the material, making it a promising candidate for proton conducting applications.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Inorganic & Nuclear
Jun-Qiang Chen, Hai-Xia Zhang, Zhi-Run Wang, Qin-Long Hong, Jian Zhang
Summary: In this study, a new MOC cage with a unique trigonal bipyramidal configuration was reported, which was constructed by the combination effects of coordination bonds and π-π interactions. The cage structure could be modulated by the metal centers, leading to diverse coordination environments and optical properties.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Inorganic & Nuclear
Ruiyan Chen, Guanghui Chen, Yanping He, Jian Zhang
Summary: In this study, a series of Ti4L6-based compounds with different structures were successfully synthesized and characterized by coordinating the tetrahedral Ti4L6 cages with alkaline-earth metal ions. The thermal stability, phase purity, UV-vis absorption spectrum, fluorescent, and third-order nonlinear-optical properties of these compounds were also investigated.
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Kalpana Chintakrinda, Nagaraju Narayanam, Guang-Hui Chen, Fei Wang, Jian Zhang, Lei Zhang
Summary: We report the discovery of inorganic toroidal and capsule titanium oxysulfate clusters through ionothermal synthesis. The ratio between geometrically different anions (tetrahedral SO(4)(2-) vs. pseudo-tetrahedral PO(3)(3-)) shows an interesting influence on the formation of cluster structure.
DALTON TRANSACTIONS
(2022)