Article
Nanoscience & Nanotechnology
Ligang Chen, Xin Liang, Dingsheng Wang, Zuobo Yang, Chun-Ting He, Wei Zhao, Jiajing Pei, Yanrong Xue
Summary: In this study, a facile dual-regulation approach was used to synthesize Ru1Ptn single atom alloy catalysts, which exhibited excellent activity in electrocatalytic reactions. Density functional theory calculations demonstrated the important role of Ru atoms in reaction energetics.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Songlin Xue, Ningchao Liu, Peifeng Mei, Daiki Kuzuhara, Mingbo Zhou, Jianming Pan, Hiroko Yamada, Fengxian Qiu
Summary: The first example of monovalent and bimetallic porphyrins was successfully obtained, showing that the rhodium complex of porphyrin could serve as a new binucleating ligand for the fabrication of bimetallic complexes under controlled conditions.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Feng Luo, Jiarui Wu, Xiaojun Chen, Liang Qiao, Xiaonan Liu, Xiaoqiang Wu
Summary: Platinum-based materials have always been dominant in direct methanol fuel cells (DMFCs) due to their high-efficiency as anode methanol oxidation catalysts. However, the strong adsorption of intermediates easily poisons the Pt-active centers and leads to significant activity loss. This study investigates the commonality between the oxygen evolution reaction (OER) and methanol oxidation reaction (MOR) mechanism in Pt/CrCoNi complex catalysts and establishes a relationship between them to screen appropriate synergistic materials and reduce activity loss. The optimized Pt/CrCoNi (7.5-225 Torr oxygen pressure and 400 degrees C annealing) film shows advanced MOR performance with a mass activity of 3785 A gPt -1 and good durability of 50000 s in alkaline solution.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Yangyang Ren, Zehao Zang, Chenhao Lv, Beibei Li, Lanlan Li, Xiaojing Yang, Zunming Lu, Xiaofei Yu, Xinghua Zhang
Summary: Highly durable and active PtCuCo nanoframes were prepared as enhanced bifunctional electrocatalysts for oxygen reduction reaction (ORR) and methanol oxidation reaction (MOR) in acidic environment. The PtCuCo nanoframes exhibited remarkable activity and durability due to their ternary compositions and structure-fortifying frame structures. The specific/mass activity of PtCuCo nanoframes for ORR in perchloric acid solution was 12.8/7.5 times as large as that of commercial Pt/C, while for MOR in sulfuric acid solution, the mass/specific activity was 5.4/9.4 times as large as that of Pt/C. This work may provide a promising nanoframe material for developing dual catalysts for fuel cells.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Green & Sustainable Science & Technology
Bo-Qiang Miao, Ya-Chong Liu, Yu Ding, Pu-Jun Jin, Pei Chen, Yu Chen
Summary: In this study, high-quality chlorine-free Rh nanodendrites (Rh-NDs) were successfully synthesized by a simple one-step chemical-reduction method. Rh-NDs exhibited high electroactivity for methanol oxidation reaction (MOR) in alkaline direct methanol fuel cells. Under optimal experimental conditions, Rh-NDs showed a significant enhancement in electroactivity and durability for MOR compared to irregular Rh nanocrystals, thanks to their dendritic morphology that provides a large specific surface area, rich corner/edge atoms, and efficient aggregation inhibition.
SUSTAINABLE MATERIALS AND TECHNOLOGIES
(2022)
Article
Chemistry, Physical
Yu Ding, Bo-Qiang Miao, Ya-Chong Liu, Nan Hou, Yun Yang, Pu-Jun Jin, Shi-Bin Yin, Yu Chen
Summary: RhCo-NTs with hollow and tubular architecture synthesized through a one-pot reduction approach show enhanced electroactivity and stability for the methanol oxidation reaction.
Article
Engineering, Chemical
Shusei Tanizume, Sota Maehara, Katsunori Ishii, Takamasa Onoki, Takuya Okuno, Hiromasa Tawarayama, Shinji Ishikawa, Mikihiro Nomura
Summary: By synthesizing a defect-free MFI zeolite membrane on a porous silica substrate, high selectivity and yield of olefins from methanol conversion can be achieved.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Fubo Gu, Xuetao Qin, Mengwei Li, Yao Xu, Song Hong, Mengyao Ouyang, Georgios Giannakakis, Sufeng Cao, Mi Peng, Jinling Xie, Meng Wang, Dongmei Han, Dequan Xiao, Xiayan Wang, Zhihua Wang, Ding Ma
Summary: In this study, atomically dispersed Rh on TiO2 suspended in an aqueous solution was used as a catalyst for the oxidation of methane to methanol. Promoted by copper cations, the catalysts showed high activity and selectivity, achieving millimole level yields of methanol with a selectivity higher than 99%.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Farshad Shiri, Alireza Ariafard
Summary: 1,6-enynes can be cyclized to yield cyclopropyl ketones using PhI(OAc)(2) (PIDA) in the presence of Pd(OAc)(2) as a catalyst. However, when 1,6-enynes are substituted by a hydroxy group at the alpha-position, polycyclic oxa-heterocycles are formed instead. This study aims to investigate the mechanistic aspects of these transformations and reveals that the change in chemoselectivity is due to the electronic nature of the Pd catalyst changing from pi-philicity to oxophilicity during the catalytic cycle.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Physical
Xiaoqu Wang, Jiuhui Qi, Xinji Luo, Zhongyun Yang, Youjun Fan, Zhe Jiang, Chengzhou Liu, Jun Yang, Wei Chen
Summary: The wet-chemistry synthesis of dendritic Au@PtIr nanowires with core-shell structures shows promising catalytic properties in methanol oxidation reaction and hydrogen evolution reaction. The unique combination of one-dimensional dendritic features and synergistic interactions in the alloy shells contribute to the enhanced catalytic performance of the nanowires.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Review
Chemistry, Organic
Ghodsi Mohammadi Ziarani, Marzieh Rad, Fatemeh Mohajer, Hitesh Sehrawat, Ravi Tomar
Summary: The analogs of 6-Amino uracil play a crucial role in biological activities and are utilized as important components in the synthesis of various heterocyclic compounds. This compound has been extensively used as a precursor in the synthesis of diverse heterocyclic cores from 2016 to 2020.
CURRENT ORGANIC CHEMISTRY
(2021)
Article
Chemistry, Physical
Sedighe Hosseini, Mohammad Bagher Askari, Hadi Beitollahi
Summary: In this study, a nanocatalyst based on nickel oxide and manganese oxide was synthesized, and it was hybridized with multi-walled carbon nanotubes using a hydrothermal method. The MnNi2O4- MWCNTs nanocatalyst showed better performance in the methanol oxidation reaction, with higher electrical conductivity and active surface. The synthesized nanocatalysts can serve as inexpensive, stable, and attractive options for methanol oxidation.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Materials Science, Multidisciplinary
Dinesh Muthu, T. Sadhasivam, Tae Hwan Oh
Summary: In this study, nickel molybdate nanorods were successfully grown on carbon cloth and exhibited excellent catalytic performance. The NiMoO4/CC showed low onset potential and notable cyclic stability in the methanol oxidation reaction. In the hydrogen evolution reaction, it demonstrated low overpotential and high turnover frequency.
Article
Chemistry, Physical
Fangfang Fan, Du -Hong Chen, Linjuan Yang, Jiuhui Qi, Youjun Fan, Yixuan Wang, Wei Chen
Summary: This study successfully synthesized tunable PtCuFe alloy nanochains by adjusting the molar ratios of metal precursors. These nanochains exhibited higher catalytic activity and stability compared to Pt nanoparticles, PtFe nanoparticles, and PtCu nanochains. Additionally, it was found that 1D PtCuFe nanochains showed the highest activity for the methanol oxidation reaction. This work establishes a foundation for the controllable synthesis of multi-metal Pt-based nanochains/alloy catalysts and their applications in other electro-catalytic reactions.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Physical
Te Zhang, Houkang Pu, Huizhen Dai, Kaiyu Dong, Kuankuan Wang, Luming Zhou, Yingying Wang, Yujia Deng
Summary: In this study, Pt-Rh trioctahedral nanocrystals with {441} high-index facets were successfully synthesized using the electrochemical square wave potential method. The balance between etching and growth was found to be crucial in achieving the desired structure, leading to enhanced catalytic activity and stability for methanol and ethanol oxidation reactions compared to commercial Pt/C catalysts.
ACS APPLIED ENERGY MATERIALS
(2022)