期刊
INORGANIC CHEMISTRY
卷 47, 期 19, 页码 8721-8726出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic800587y
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资金
- EPSRC
- NSERC
- STFC [CC/D00005X/1] Funding Source: UKRI
- Science and Technology Facilities Council [CC/D00005X/1] Funding Source: researchfish
Aluminum(III) porphyrin carboxylate complexes have shown an affinity for a sixth nitrogenous ligand. The use of isonicotinic or nicotinic acid, which offers both a carboxylate and a nitrogen donor in the same molecule, resulted in the formation of one-dimensional (1-D) coordination polymers. The complexes and their linear oligomers have been characterized by H-1 NMR spectroscopy and nanoelectrospray ionization spectrometry. X-ray analyses confirmed the formation of the 1-D polymers in the solid state.
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