期刊
INORGANIC CHEMISTRY
卷 47, 期 20, 页码 9128-9130出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic801314s
关键词
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资金
- MEC [MAT2007-66476-C02-02, MAT2007-61584 NAN2004-09183-C10-05/06, FP6-029192, CTQ2005-00397/BQU, CTQ2006-027185-E, CSD 2007-00010]
- Comunidad de Madrid [S-0505/MAT/0303]
We report on a novel highly semiconducting 1D coordination polymer architecture obtained by the reaction of a Cull salt with 2,2'-dipyridyldisulfide under microwave solvothermal conditions. This reaction proceeds with an unusual C-S and S-S bond cleavage of the 2,2'-dipyridyldisulfide ligand. The unprecedented architecture of this coordination polymer consists of a 1D chain formed by the assembling of Cu-9 cluster cages. The electrical conductivity behavior of this novel material suggests new perspectives for the use of coordination polymers as electrical conducting materials.
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