Review
Chemistry, Physical
Zhen Liu, Longjiang Deng, Bo Peng
Summary: This review focuses on the latest research of 2D ferromagnetic and ferroelectric materials, discussing their fundamental properties and limitations in practical applications. Strategies to address these limitations are proposed, and the potential for multifunctional devices through vdW heterostructures is explored.
Article
Chemistry, Physical
Ruhul Amin, Koyalsuman Samantaray, Saniya Ayaz, Sachindra N. Sarangi, Indranil Bhaumik, Somaditya Sen
Summary: Polycrystalline Ba0.75Pb0.25Ti1-xFexO3 (0 <= x <= 0.148) (BPTF) ceramics were synthesized using the sol-gel auto combustion method. The structural, vibrational, electrical, and magnetic properties were investigated. The presence of both tetragonal and hexagonal phases was observed, with an increase in the hexagonal phase in higher Fe-doped samples. A relaxor-type phase transition was observed in the high Fe-doped samples. The samples exhibited ferroelectric properties at room temperature, as confirmed by the presence of room-temperature P-E hysteresis loops. Additionally, higher Fe-doped samples showed increased ferromagnetic ordering at room temperature. Therefore, the Fe-doped Ba0.75Pb0.25TiO3 system exhibited multiferroic properties at room temperature.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Review
Chemistry, Multidisciplinary
Junwei Chu, Yang Wang, Xuepeng Wang, Kai Hu, Gaofeng Rao, Chuanhui Gong, Chunchun Wu, Hao Hong, Xianfu Wang, Kaihui Liu, Chunlei Gao, Jie Xiong
Summary: The emergence of 2D polarized materials has demonstrated unique quantum behaviors at atomic scales and their applications in information storage and processing have developed significantly in recent years. This review focuses on the basic 2D polarized materials system and their applications in spintronics, valleytronics, and electronics, highlighting the underlying physical mechanisms, symmetry broken theory, and modulation process through heterostructure engineering. These summarized works will continue to enrich the understanding of 2D quantum systems and promising practical applications.
ADVANCED MATERIALS
(2021)
Review
Chemistry, Physical
Jiawei Wang, Aitian Chen, Peisen Li, Sen Zhang
Summary: Electric-field control of magnetism is crucial for the next generation of data storage technology. Researchers have explored the electric-field control of magnetism via strain coupling, especially in heterostructures like CoFeB/PMN-PT. Recent experiments in magnetic tunnel junctions/FE architecture show promising results in nonvolatile and reversible electric-field control of tunneling magnetoresistance, indicating great potential for future data storage technology.
Review
Chemistry, Physical
Ganesha Channagoudra, Vijaylakshmi Dayal
Summary: This paper emphasizes the progress on magnetoelectric coupling and the impact of charge and strain in composite heterostructures. The direct and converse magnetoelectric effect on improving the magnetoelectric coefficient is discussed. Furthermore, a brief overview of devices based on multiferroic magnetoelectric materials and their future perspectives is presented.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Polymer Science
Liudmila A. Makarova, Danil A. Isaev, Alexander S. Omelyanchik, Iuliia A. Alekhina, Matvey B. Isaenko, Valeria V. Rodionova, Yuriy L. Raikher, Nikolai S. Perov
Summary: Multiferroics are materials that exhibit unique properties under the influence of magnetic and electric fields, achieved through a combination of ferromagnetic and ferroelectric particles. In soft polymer matrices, the separation of particles results in a more complex multiferroic coupling compared to solid composites.
Article
Nanoscience & Nanotechnology
Liming Chen, Jian Zhou, Xiao Zhang, Kuankuan Ding, Jianxiang Ding, Zhengming Sun, Xuefeng Wang
Summary: This study investigates the influence of quantum interference effects on tunneling electroresistance in La0.7Sr0.3MnO3/BaTiO3/Nb:SrTiO3 FTJs at low temperatures. It is found that the ON/OFF current ratio can be significantly enhanced by manipulating the ferroelectric polarization effect.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Ping Li, Xue-Song Zhou, Zhi-Xin Guo
Summary: This study proposes a method to efficiently control 2D magnets with a small electric field in a multiferroic heterostructure. The feasibility of this strategy is demonstrated in the bilayer CrI3/BiFeO3(001) heterostructure using first-principles calculations. The heterostructure exhibits strong magnetoelectric coupling, allowing efficient switching between ferromagnetic and antiferromagnetic states of the bilayer CrI3 by the polarized states of BiFeO3(001).
NPJ COMPUTATIONAL MATERIALS
(2022)
Review
Chemistry, Organic
Hsien-Cheng Yu, Neal P. Mankad
Summary: This review summarizes recent advances in homogeneous catalysis using heterobimetallic carbonyl catalysts with polar metal-metal interactions, covering hydrogenation, hydrofunctionalization, carbonylation, carboxylation, and oxidative transformations.
SYNTHESIS-STUTTGART
(2021)
Article
Chemistry, Physical
Junlei Zhao, Xinyu Wang, Haohao Chen, Zhaofu Zhang, Mengyuan Hua
Summary: This work systematically studies the structural, electronic, and optical properties of a 2D ferroelectric Ga2O3 bilayer system. It reveals the high tunability of the bilayer system under interlayer perturbation and biaxial strain, as well as a phase transition from vdW to ionic interlayer interaction induced by in-plane biaxial tensile strain. These insights hold significant prospects for experimental synthesis, characterization, and application of 2D Ga2O3 atomically thin layered systems.
CHEMISTRY OF MATERIALS
(2022)
Article
Materials Science, Ceramics
S. A. Sharko, A. I. Serokurova, N. N. Novitskii, N. N. Poddubnaya, V. A. Ketsko, A. I. Stognij
Summary: This article demonstrates that the elastic strains at the interface in layered structures of thin cobalt, nickel, and permendur layers on ferroelectric ceramics substrates have a more significant impact on the magnetoelectric effect than the magnetostriction of the ferromagnetic layer. These structures, obtained through ion-beam sputtering and planarization, exhibit higher magnetoelectric voltage coefficient for cobalt than for nickel and permendur. They also have thermosability within the temperature range of 25 to +120 degrees Celsius and reproducible magnetoelectric properties, making them suitable for magnetoelectric converters and magnetic field sensors.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Multidisciplinary
Shereef A. Fareed, Makram Ibrahim, Ahmed E. Hannora, M. M. El-Desoky
Summary: Nano-crystalline bismuth manganese oxide Bi2Mn4O10 was prepared by mechanochemical technique and subsequently heat treated. The experiment revealed the crystal structure, variation of crystallite size and micro-strain with milling time, as well as the magnetic parameters, electrical conductivity and dielectric parameters at different temperatures and frequencies.
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
(2022)
Article
Chemistry, Multidisciplinary
Grzegorz Vetter, Agata Bialonska, Aneta Jezierska, Jaroslaw J. Panek, Ewa Pacholska-Dudziak
Summary: Two core-modified porphyrins containing platinum(ii) or platinum(iv) and rhodium(iii) have been obtained by modifying the 21,23-ditelluraporphyrin. The two molecules exhibit different degrees of metal-metal interaction depending on the oxidation state of platinum, with NBO bond orders of 0.04 for platinum(iv) and 0.15 for platinum(ii).
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Wenxuan Wang, Wei Sun, Hang Li, Ying Bai, Fengzhu Ren, Caiyin You, Zhenxiang Cheng
Summary: This research focuses on nonvolatile electrical control of magnetism in 2D van der Waals materials, specifically by designing a multiferroic heterostructure with a CrOBr ferromagnetic bilayer and an In2Se3 ferroelectric monolayer. The weaker interlayer exchange coupling in the CrOBr bilayer allows for easier regulation by ferroelectric polarization, enabling reversible shifts between ferromagnetic and antiferromagnetic ordering. This electrically controlled interlayer magnetic coupling may have practical applications in high-sensitivity sensors and high-density data storage using 2D vdW bilayer magnets.
Article
Physics, Applied
Dier Feng, Ziye Zhu, Xiaofang Chen, Jingshan Qi
Summary: The study highlights the importance of magnetoelectric coupling in understanding physics and applications, proposing a novel heterostructure design with potential magnetic and electrical property modifications. The results suggest that such structures could serve as a strategy for designing spin-current-based nonvolatile memory structures.
APPLIED PHYSICS LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Xiao Liang, Xu-Feng Luo, Zhi-Ping Yan, You-Xuan Zheng, Jing-Lin Zuo
Summary: A novel OLPL system was proposed using a melt-casting method with 0.1 mol% of Cu-I complexes doped into a TPP host, achieving an afterglow duration of over 3 hours. The OLPL lifetime can be modulated by different halogen atoms, marking a rare example of OLPL initiated through host-guest coordination with potential for expanding design strategies in this field.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Chang Liu, Rui Cheng, Jiazhuang Guo, Ge Li, He Li, Hong-Gang Ye, Zhi-Bin Liang, Cai-Feng Wang, Su Chen
Summary: Carbon dots (CDs) are promising carbon-based fluorescent nanomaterials with wide application prospects. The CDs prepared from citric acid and carbamide through magnetic hyperthermia treatment exhibit high photoluminescence quantum yield and good dispersibility. The large-area fluorescent nanofiber films embedded with CDs and polymer matrixes show dramatically enhanced mechanical properties.
CHINESE CHEMICAL LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Jiazhuang Guo, Yushuang Lu, An-Quan Xie, Ge Li, Zhi-Bin Liang, Cai-Feng Wang, Xiaoning Yang, Su Chen
Summary: This study reports the synthesis, properties, and potential applications of yellow-emissive carbon dots (Y-CDs) with high photoluminescence quantum yield (PL QY). Y-CDs were prepared through solvothermal treatment and column chromatography, and exhibited excitation-independent PL emission with a high PL QY of 92%. Various characterizations and calculations were conducted to confirm the structure of Y-CDs, and Y-CD films with high PL brightness were fabricated.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Jin Zhao, Ji-Dong Liu, Haixia Shen, Min Guo, Qing Li, Cai-Feng Wang, Chang Liu, Su Chen
Summary: This study achieved a significant breakthrough in the mechanical properties of hydrogels by designing a unique structure. The hydrogel with gradient structure and high swelling ratio can mimic artificial muscles to perform various moving activities.
ACS APPLIED POLYMER MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Rui Cheng, Zhi-Bin Liang, Liangliang Zhu, Hao Li, Yi Zhang, Cai-Feng Wang, Su Chen
Summary: Nano-/micro-reactors are widely used for chemical synthesis, and this study introduces a new fiber-spinning chemistry technique for large-scale production of nanoreactors. The nanoreactors, including ligand-free perovskite quantum dots, exhibit high photoluminescence quantum yield, tunable emissive peaks, and excellent photoluminescence stability. These nanoreactor-fiber films have potential applications in CO2 conversion, wide-color-gamut displays, and LED devices.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Materials Science, Multidisciplinary
Lintao Chen, He Li, Luting Ling, Jiazhuang Guo, Haixia Shen, Cai-Feng Wang, Su Chen
Summary: By doping graphene oxide during the synthesis process of CdTe quantum dots, the GO-CdTe nanocomposites with layered structure and well-preserved CdTe quantum dots were successfully prepared, showing interesting optical properties and enhanced photoelectric performance in solar cells.
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
(2022)
Article
Materials Science, Multidisciplinary
Chang Liu, Hongying Li, Rui Cheng, Jiazhuang Guo, Guo-Xing Li, Qing Li, Cai-Feng Wang, Xiaoning Yang, Su Chen
Summary: In this study, a facile strategy for fabricating high-performance carbon dots (CDs) for various applications, including metal ion detection, fluorescent printing, and flame retardant materials, is reported. The CDs are synthesized through solvothermal treatment and show excellent performance when incorporated into polymers.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2022)
Review
Polymer Science
Qing Li, Hai-Xia Shen, Chang Liu, Cai-Feng Wang, Liangliang Zhu, Su Chen
Summary: This paper provides an overview of the current development of frontal polymerization (FP) technology, including three traditional FP models and newly developed methods. The applications of FP in various synthesis areas, such as nanocomposites, gradient materials, and resins, are discussed. The challenges and future perspectives of FP are also addressed.
PROGRESS IN POLYMER SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Tingting Cui, Jiafei Yu, Cai-Feng Wang, Su Chen, Qing Li, Kun Guo, Renkun Qing, Gefei Wang, Jianan Ren
Summary: This work presents a microfluidic assembly technique to fabricate micro-gel ensembles that can precisely tune the pH value of wound surface and accelerate wound healing. By regulating the wound pH, the physiological processes are greatly facilitated, resulting in much accelerated healing of chronic wounds.
Article
Materials Science, Multidisciplinary
Zi-Liang He, Ji-Dong Liu, Jie Hu, Cai-Feng Wang, Qing Li, Gefei Wang, Su Chen
Summary: This study reports a self-healing assembly strategy for pH-regulated gel wound dressing. The Gel 1/Gel 2 bilayer exhibits different bending behaviors based on reverse pH sensitivity, providing opportunities for pH regulation and accelerating wound healing.
JOURNAL OF MATERIALS SCIENCE
(2022)
Article
Polymer Science
Yue Yang, Jie Hu, Ji-Dong Liu, Ying Qin, Jian Mao, Yunzheng Liang, Gefei Wang, Haixia Shen, Cai-Feng Wang, Su Chen
Summary: In this study, a rapid frontal polymerization (FP) method was used to synthesize bilayer hydrogels with good water swelling, mechanical strength, self-healing ability, biocompatibility, and antibacterial capability. The hydrogels exhibited hierarchical porous morphology and versatile functions.
JOURNAL OF POLYMER SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Xu Chen, Ying Qin, Xinru Song, He Li, Yue Yang, Jiazhuang Guo, Tingting Cui, Jiafei Yu, Cai-Feng Wang, Su Chen
Summary: This study reports a new synthesis method for forsythia-derived carbon dots (F-CDs) and their incorporation into Nylon-11 nanofibers for improved mechanical properties and biocompatibility. The F-CDs were prepared from forsythia herb and embedded into Nylon-11 nanofibers, leading to significantly enhanced tensile strength and elongation ratio. Additionally, the F-CD nanofibers exhibited excellent cytocompatibility.
Article
Polymer Science
Ying Qin, Hao Li, Hai-Xia Shen, Cai-Feng Wang, Su Chen
Summary: This paper presents a fast, energy-efficient, and convenient method of frontal polymerization (FP) for the rapid fabrication of new hydrogels with super water swelling capacity and self-healing ability. The resulting hydrogels, poly(AM-co-SBMA-co-AA), exhibit high transparency, stretchability, and sensitivity to pH. The properties of the hydrogels can be tuned by adjusting the monomer ratio, making them highly versatile in various applications.
Article
Materials Science, Multidisciplinary
Zhi-Bin Liang, Xu Chen, Xiang-Ji Liao, Jing-Jing Li, Yue Yang, Cai-Feng Wang, You-Xuan Zheng, Su Chen
Summary: In this study, we successfully synthesized stable chiral perovskite nanocrystals (PNCs) with high photoluminescence quantum yields (PL QYs) and circularly polarized luminescence (CPL) using the fiber-spinning chemistry (FSC) method. By modifying the surface defects of PNCs and encapsulating them in PAN nanofibers, the resulting nanofiber films exhibited excellent optical properties and stability.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
Ge Li, Hao Li, Jiang Zhai, Jiazhuang Guo, Qing Li, Cai-Feng Wang, Su Chen
Summary: A visual microfluidic detection platform using CdTe quantum dots was developed for rapid and sensitive detection of veterinary drugs. The CdTe QDs showed selective fluorescence response to specific veterinary drugs, with different ligands displaying varying degrees of response. The platform offers simple operation, low cost, rapid sensing, and good sensitivity for quantitative detection of veterinary drug residues.