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Chemistry, Inorganic & Nuclear
Raoudha Soury, Mahjoub Jabli, Khalaf M. Alenezi, Marwa Chaabene, Ashanul Haque, Hani El Moll, Regis Rein, Eid M. S. Azzam, Nathalie Solladie
Summary: A new metalloporphyrin complex was successfully synthesized and its ability to degrade organic dyes in aqueous solution was explored. The study demonstrated that the degradation ability of a metalloporphyrin complex can be fine-tuned by varying axial ligands.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
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Biochemistry & Molecular Biology
Toshio Nishino, Yasuyuki Yamada, Ayumi Yamamoto, Kentaro Tanaka
Summary: A novel double-decker porphyrin complex with reversible redox behavior was prepared and shown to exhibit redox switching between oxidized and reduced states in organic solvents.
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Polymer Science
Jhon Puerres, Mauro Diaz, John Hurtado, Pablo Ortiz, Maria T. Cortes
Summary: Cobalt porphyrins are promising catalysts for electrochemical and photoelectrochemical applications due to their excellent performance, low cost, and abundance on Earth. Immobilizing negatively charged TPPS in PPy and metallizing it with cobalt to obtain CoTPPS had different effects on the photoelectrochemical behavior towards thiosulfate oxidation and oxygen reduction. The findings are important for understanding the role of CoTPPS as a catalyst in applications like water splitting and could contribute to the design of novel photocathodes.
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Polymer Science
Shaila Pervin, Chironjit Kumar Shaha, Subarna Karmaker, Tapan Kumar Saha
Summary: Chitosan successfully conjugates with Zn(tpps) to inhibit its demetallization and aggregation in acidic solution. The conjugation process follows pseudo-second-order kinetics and Langmuir isotherm model, with a maximum binding capacity of 151.52 µmol/g.
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Chemistry, Multidisciplinary
Chironjit Kumar Shaha, Bithy Sarker, Shurid Kishore Mahalanobish, Md. Sharif Hossain, Subarna Karmaker, Tapan Kumar Saha
Summary: This study investigated the conjugation of chitosan with the insulin-mimetic VO(tpps) in an aqueous medium. The conjugate formation was found to be attributed to the electrostatic interaction between the NH3+ units of chitosan and the SO3- units of VO(tpps). It was also found that chitosan enhances the stability of VO(tpps) in water. The conjugation reaction was best explained by pseudo-second-order kinetic and Langmuir isotherm models.
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Chemistry, Physical
Maria -Lydia Vorvila, Ioanna K. Sideri, Anastasios Stergiou, Martha Kafetzi, Stergios Pispas, Raul Arenal, Nikos Tagmatarchis
Summary: This study presents a surface engineering approach to modify graphene oxide and enhance its intrinsic electrocatalytic activity towards the oxygen reduction reaction (ORR) without using any metals. The results showed that both covalent and non-covalent surface engineering of graphene with organic chains play an important role in electrocatalysis and should not be ignored.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
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Chemistry, Multidisciplinary
Ahmed A. AboAlhasan, Mahmoud A. S. Sakr, Mostafa F. Abdelbar, Hamdy S. El-Sheshtawy, Samy A. El-Daly, El-Zeiny M. Ebeid, Rania Hussien Al-Ashwal, Sadeq M. Al-Hazmy
Summary: This study demonstrates the enhancement of energy transfer in porphyrin derivatives for photodynamic therapy (PDT) through the use of metallic silver nanoparticles (AgNPs).
JOURNAL OF SAUDI CHEMICAL SOCIETY
(2022)
Article
Chemistry, Inorganic & Nuclear
Patrick J. Desrochers, Adam J. Pearce, T. Ryan Rogers, Jeremy S. Rodman
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2016)
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Chemistry, Inorganic & Nuclear
Patrick J. Desrochers, Adam L. Corken, Richard M. Tarkka, Brian M. Besel, Erin E. Mangum, Tiffany N. Linz
INORGANIC CHEMISTRY
(2009)
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Chemistry, Inorganic & Nuclear
Patrick J. Desrochers, Brian M. Besel, Adam L. Corken, Jared R. Evanov, Andrea L. Hamilton, David L. Nutt, Richard M. Tarkka
INORGANIC CHEMISTRY
(2011)
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Chemistry, Inorganic & Nuclear
Patrick J. Desrochers, Christopher A. Sutton, Micah L. Abrams, Shengfa Ye, Frank Neese, Joshua Telser, Andrew Ozarowski, J. Krzystek
INORGANIC CHEMISTRY
(2012)
Article
Chemistry, Inorganic & Nuclear
Charles A. Mebi, Joshua J. Trujillo, Britney L. Rosenthal, Robert B. Bowman, Bruce C. Noll, Patrick J. Desrochers
TRANSITION METAL CHEMISTRY
(2012)
Article
Chemistry, Inorganic & Nuclear
Patrick J. Desrochers, Ali Abdulrahim, Katherine R. Demaree, Joseph A. Fortner, Jamie D. Freeman, Makenzie Provorse Long, Madison E. Martin, Carlos J. Gomez-Garcia, Nikolay Gerasimchuk
Summary: The optical, structural, and magnetic properties of iron(II,III) sandwich complexes, Fe(Tp ')2n+ (Tp ' = bis(3,5-dimethylpyrazolyl)benzotriazolylborate), are described. The intensely colored FeII(Tp ')2 (orange) and FeIII(Tp ')2+ (purple) show strong MLCT bands. Geometric isomerism for M(Tp ')2 is established crystallographically in the racemate of chiral cis-Fe(Tp ')2. For the first time, paramagnetic 11B NMR describes solution-phase low-spin (LS, S 0) to high-spin (HS, S = 2) crossover behavior in Fe(Tp ')2. Thermochemical parameters for solution-phase SCO of Fe(Tp ')2 demonstrate the endothermic LS to HS conversion and entropic preference of the HS state. Entropy changes for both Fe(Tp ')2 isomers are significantly larger than for the majority of iron scorpionate SCO systems. Solid-state magnetic and thermochemical measurements show cis-Fe(Tp ')2 to be thermally stable up to 520 K, allowing experimental investigation of a solid-state SCO magnetic hysteresis of over 45 K. A large solution vs solid-state SCO difference was observed: cis-Fe(Tp ')2 shows Tc Pe. 270 K (solution) and Tc Pe. 385 K (solid), with the remarkably wide Delta Tc Pe. 115 K; trans-Fe(Tp ')2 shows Tc Pe. 278 K (solution) and Tc Pe. 372 K (solid). Solid-state Tc values are among the highest seen for iron(II) molecular systems. The large solution/solid Delta Tc difference is explained by anchoring intermolecular interactions in the solid state that prevent thermal expansion of the LS iron(II) coordination sphere in its transition to the HS state. DFT calculations, validated against LS cis-Fe(Tp ')2 crystallography and LS to HS SCO thermochemical parameters, demonstrate the role the benzotriazole rings play in its structural and optical properties. The Lewis basicity of M(Tp ')2 is shown with the structural characterization of the air-stable tin(II) adduct [cis-Fe(Tp ')2-SnCl2]; tin(II) coordination does not alter the iron(II) spin state. The Tp ' chelate adds functionality (asymmetry, chirality, chemical reactivity) to the array of iron SCO materials for potential incorporation into nanoscale magnetic switches and spintronic devices.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Patrick J. Desrochers, Davis S. Duong, Ariel S. Marshall, Stacey A. Lelievre, Bonnie Hong, Josh R. Brown, Richard M. Tarkka, Jerald M. Manion, Garen Holman, Jon W. Merkert, David A. Vicic
INORGANIC CHEMISTRY
(2007)
Article
Chemistry, Inorganic & Nuclear
Patrick J. Desrochers, Joshua Telser, S. A. Zvyagin, Andrew Ozarowski, J. Krzystek, David A. Vicic
INORGANIC CHEMISTRY
(2006)
Article
Chemistry, Multidisciplinary
Gavin D. Jones, Jason L. Martin, Chris McFarland, Olivia R. Allen, Ryan E. Hall, Aireal D. Haley, R. Jacob Brandon, Tatyana Konovalova, Patrick J. Desrochers, Peter Pulay, David A. Vicic
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2006)
Article
Crystallography
PJ Desrochers, JR Brown, ME Arvin, GD Jones, DA Vicic
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
(2005)
Article
Chemistry, Inorganic & Nuclear
PJ Desrochers, S LeLievre, RJ Johnson, BT Lamb, AL Phelps, AW Cordes, WW Gu, SP Cramer
INORGANIC CHEMISTRY
(2003)