期刊
INDUSTRIAL CROPS AND PRODUCTS
卷 62, 期 -, 页码 84-93出版社
ELSEVIER
DOI: 10.1016/j.indcrop.2014.08.010
关键词
Polycondensation; Maritime pine bark; Phenolic resins; Aldehydes
资金
- WoodWisdom-Net Research Program
- ERA-NET Bioenergy
- Federal Ministry of Food, Agriculture and Consumer Protection through the Agency for Renewable Resources in Germany
- Deutsche Forschungsgemeinschaft
Tannin-based resins were prepared by acid-catalized polycondensation of maritime pine (Pinus pinaster Aft.) bark condensed tannin (CTs) and several aldehydes (A) in different molar ratio (CTs:A, 1.0:0.5; 1.0:1.0; 1.0:1.5) to assess the impact of the aldehyde chain structure on the novolac properties. The resin systems were characterized in term of reactivity, structural, morphological and thermal properties. Systematic relationships between aldehyde chain length and C-stage resin properties were established. When alkyl aldehydes with increasing chain lengths were used, reactivity with CTs decreased while C-stage resins exhibited systematic increases in bulk density, T-g and thermal stability. For the di-aldehydes and alpha beta-unsaturated aldehyde series, opposite trends were observed. This study on tannin-based novolacs demonstrates the potential to tailor aldehyde/tannin reactivity and C-stage resin properties in a systematic manner as a function of aldehyde chain length, functionality and unsaturation degree. (C) 2014 Elsevier B.V. All rights reserved.
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