Article
Materials Science, Ceramics
Qinyan Yang, Xiang Yao, Hualing Tian, Yanjun Cai, Zhi Su
Summary: The introduction of fast ion conductor LVP into LVOP enhances electronic conductivity and first discharge specific capacity of the composite material, leading to improved cycle performance. The presence of both LVOP and LVP phases with carbon coating in the synthesized material contributes to the increase in Li+ pervasion channels and acceleration of Li+ transmission speed, further boosting electrochemical performance.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Analytical
Duyoung Choi, Ji-Yeon Shim, Sungwoong Choi, Sangmin Park, Harok Jeong, Min -Su Kim, Jungpil Kim, Junghoon Yang
Summary: Alkali vanadium phosphates are promising electrode materials for next-generation ion batteries, but suffer from low electronic conductivity due to phosphate group. In this study, a method of building an effective carbon backbone in alkali vanadium phosphate and carbon composite is proposed to overcome this issue. The carbon backbone not only provides electron pathways but also suppresses particle agglomeration, resulting in efficient ion diffusion and electron transfer. The importance of efficient carbon composite materials for phosphate-based electrode materials is demonstrated by investigating the rhombohedral Li3V2(PO4)3 material as a cathode and anode for lithium-ion batteries, which is a different phase from the well-known monoclinic Li3V2(PO4)3.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2023)
Article
Electrochemistry
Limin Zhu, Lulu Mo, Lingling Xie, Xiaoyu Cao
Summary: In this study, a simple and efficient synthetic route was developed to prepare LZO-LVPC composites by mechanically ball-milling. The composites showed improved electrochemical performance, with enhanced charge transfer and diffusion of Li+ compared to pristine LVPC. This synthetic method is convenient for large-scale production.
ELECTROCHEMISTRY COMMUNICATIONS
(2021)
Article
Electrochemistry
Hwang Sheng Lee, Vishwanathan Ramar, Saravanan Kuppan, Mangayarkarasi Nagarathinam, Markas Law, Chen Wang, Abhinav Tripathi, Palani Balaya
Summary: The one-pot soft template synthesis of alpha-Li3V2(PO4)(3)/C shows excellent storage and rate performances, with unique morphology and long cycle life. This cathode material demonstrates high discharge capacities and better rate performance compared to known cathode materials for lithium-ion batteries.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Physical
Jie Lu, Yiqin Wang, Fuyu Song, Zepeng Zhang, Qiuwei Lu, Yi Cheng, Yehan Tao, Jian Du, Haisong Wang
Summary: In this study, a carbonaceous layer rich in oxygen-containing functional groups was successfully synthesized from N-doped lignin waste liquor and used as an armor layer to decorate the LVP cathode material, thereby improving the capacity and lifespan of lithium-ion batteries. The champion device exhibited a high initial discharge capacity and excellent capacity retention at high rates.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Multidisciplinary
Lulu Mo, Limin Zhu, Lingling Xie, Xiaoyu Cao
Summary: This study reports the preparation of Cu-coated Li3V2(PO4)3/C composites via a chemical precipitation and self-reduction method. The optimized Cu coating content significantly enhances the electrochemical properties, leading to higher initial discharge capacity and improved cycling stability. Enhanced performance is attributed to the uniform coating of Cu on the surface of LVPC, promoting electron transfer and Li+ ion extraction/insertion.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2021)
Article
Chemistry, Physical
Dexing Zhao, Lulu Mo, Qing Han, Lingling Xie, Limin Zhu, Xiaoyu Cao
Summary: The study synthesized a series of novel N-doped carbon-coated Li3V2(PO4)(3) composites by rheological phase method, with N-doping improving the structural stability and electrochemical performance of LVPC. The best properties were achieved when the ratio of citric acid to melamine was 5:3.
Article
Chemistry, Physical
Xiaohan Li, Ning Wang, Tong Su, Yujun Chai
Summary: Three-dimensional carbon network supported LVP and NVP composites were successfully prepared. These composites exhibit good lithium and sodium storage performance. A noticeable solid electrolyte interphase film was detected in the LVP/C electrode during cycling.
APPLIED SURFACE SCIENCE
(2022)
Article
Materials Science, Ceramics
Hsing- Hsiang, Bi -Ru Cai, Sheng-Heng Chung, Li-Wen Chu, Jing -Ru Tseng, Yue-Ming Shen
Summary: The monoclinic lithium vanadium phosphate (LVP) is a promising cathode material for lithium-ion batteries due to its high theoretical specific capacitance, high operating voltage, good ionic conductivity, and thermal stability. Synthesizing the pure LVP phase requires complicated procedures, but can be achieved through heat treatment of glass powder produced using the double crucible method. Carbon coating can improve the electrical conductivity and electrochemical properties of LVP.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Multidisciplinary
Xiaopeng Li, Xingyu Du, Yulin Xu, Jianming Li, Yujue Wang, Yan Meng, Dan Xiao
Summary: A three-dimensional holey graphene enwrapped Li3V2(PO4)(3)/N-doped carbon nanocomposite was successfully synthesized, which exhibited excellent electrochemical performance and showed potential for application in Li-ion batteries.
Article
Materials Science, Ceramics
Zan Huang, Peifang Luo, Honghong Zheng
Summary: In this work, a facile method was proposed to fabricate Ti4+-doped Li3V2(PO4)3/C nanofibers, and the Ti4+ doping contributed to the improved electrical conductivity and Li+ diffusion coefficient, resulting in good battery characteristics.
CERAMICS INTERNATIONAL
(2022)
Article
Engineering, Environmental
Siyuan Chen, Ni Wen, Chunmao Huang, Youzhong Dong, Quan Kuang, Qinghua Fan, Yanming Zhao
Summary: This study demonstrates for the first time a feasible rechargeable organic nickel ion battery using an ether-based electrolyte, Li3V2(PO4)(3) as cathode, and nickel foam as anode materials. The battery exhibits high reversible specific capacity and stable cycle performance, and the reversible insertion and extraction of Ni2+ ions into the cathode structure are confirmed by experimental methods. Additionally, the reaction mechanism and structural changes during the cycle process are analyzed in detail using in-situ X-ray diffraction technology and Rietveld refinement.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Applied
Manling Ding, Chen Cheng, Qiulong Wei, Yue Hu, Yingying Yan, Kehua Dai, Jing Mao, Jinghua Guo, Liang Zhang, Liqiang Mai
Summary: This study demonstrates the remarkable high-rate capability and long-term cycling performance of carbon decorated Li3V2(PO4)(3) cathode. Through spectroscopic analysis, the reversible evolution of V-O hybridization strength in LVP/C during the discharge-charge processes is identified as a key factor contributing to its outstanding electrochemical performance. This research not only provides an effective synthesis strategy but also deeper insights into the surface and bulk electrochemical reaction mechanism of LVP, which could benefit the further design of high-performance LVP electrode materials.
JOURNAL OF ENERGY CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Haiyan Yan, Minhao Li, Yuqiao Fu, Shujuan Chen, Yi Wang, Bo Zhang
Summary: In this study, a facile method was proposed to fabricate conductive polypyrrole-enhanced LVPO composite, and its morphology, microstructure, phase structure, and battery performance were systematically investigated. The results demonstrate that the composite exhibits superior lithium storage performance due to the synergistic effects of nanosized LVPO particles and conductive polypyrrole film.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2022)
Article
Chemistry, Physical
Feng Xiao, Ying Meng, Zhiping Lin, Yu Lei, Xianghong Chen, Jiakui Zhang, Haiying Lu, Yiping Tong, Guocong Liu, Jiantie Xu
Summary: In this study, a method to synthesize holey graphene with boron doping has been reported. The resulting boron-doped holey graphene as a cathode material in rechargeable lithium oxygen batteries exhibited excellent electrochemical performance with high capacity and long cycling stability.
Article
Instruments & Instrumentation
Andrew M. Crawford, Aniruddha Deb, James E. Penner-Hahn
JOURNAL OF SYNCHROTRON RADIATION
(2019)
Article
Chemistry, Multidisciplinary
Karl J. Koebke, Fangting Yu, Casey Van Stappen, Tyler B. J. Pinter, Aniruddha Deb, James E. Penner-Hahn, Vincent L. Pecoraro
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2019)
Article
Chemistry, Physical
Lindsay B. Michocki, Nicholas A. Miller, Roberto Alonso-Mori, Alexander Britz, Aniruddha Deb, James M. Glownia, April K. Kaneshiro, Arkaprabha Konar, Jake Koralek, Joseph H. Meadows, Danielle L. Sofferman, Sanghoon Song, Megan J. Toda, Tim B. van Driel, Pawel M. Kozlowski, Kevin J. Kubarych, James E. Penner-Hahn, Roseanne J. Sension
JOURNAL OF PHYSICAL CHEMISTRY B
(2019)
Article
Chemistry, Physical
Abdoulaye Djire, Priyanka Pande, Aniruddha Deb, Jason B. Siegel, Olabode T. Ajenifujah, Lilin He, Alice E. Sleightholme, Paul G. Rasmussen, Levi T. Thompson
Article
Chemistry, Physical
Nicholas A. Miller, Lindsay B. Michocki, Roberto Alonso-Mori, Alexander Britz, Aniruddha Deb, Daniel P. DePonte, James M. Glownia, April K. Kaneshiro, Christoph Kieninger, Jake Koralek, Joseph H. Meadows, Tim B. van Driel, Bernhard Kraeutler, Kevin J. Kubarych, James E. Penner-Hahn, Roseanne J. Sension
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2019)
Article
Chemistry, Physical
Nicholas A. Miller, Lindsay B. Michocki, Arkaprabha Konar, Roberto Alonso-Mori, Aniruddha Deb, James M. Glownia, Danielle L. Sofferman, Sanghoon Song, Pawel M. Kozlowski, Kevin J. Kubarych, James E. Penner-Hahn, Roseanne J. Sension
JOURNAL OF PHYSICAL CHEMISTRY B
(2020)
Article
Chemistry, Multidisciplinary
Tyler B. J. Pinter, Elizabeth C. Manickas, Audrey E. Tolbert, Karl J. Koebke, Aniruddha Deb, James E. Penner-Hahn, Vincent L. Pecoraro
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2020)
Article
Chemistry, Multidisciplinary
Karl J. Koebke, Victor Sosa Alfaro, Tyler B. J. Pinter, Aniruddha Deb, Nicolai Lehnert, Cedric Tard, James E. Penner-Hahn, Vincent L. Pecoraro
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2020)
Article
Chemistry, Inorganic & Nuclear
Olivia McCubbin Stepanic, Jesse Ward, James E. Penner-Hahn, Aniruddha Deb, Uwe Bergmann, Serena DeBeer
INORGANIC CHEMISTRY
(2020)
Article
Chemistry, Multidisciplinary
Zhu Li, Romila Mascarenhas, Umar T. Twahir, Albert Kallon, Aniruddha Deb, Madeline Yaw, James Penner-Hahn, Markos Koutmos, Kurt Warncke, Ruma Banerjee
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2020)
Article
Biochemistry & Molecular Biology
Karl J. Koebke, Alison G. Tebo, Elizabeth C. Manickas, Aniruddha Deb, James E. Penner-Hahn, Vincent L. Pecoraro
Summary: The study found that designing a CuHis(3) binding site within an antiparallel three helical bundle scaffold can lead to enhanced activity compared to a similar construct in parallel coiled coils. However, incorporating more complex designs or repositioning the binding site may decrease this activity.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Tyler B. J. Pinter, Leela Ruckthong, Jeanne A. Stuckey, Aniruddha Deb, James E. Penner-Hahn, Vincent L. Pecoraro
Summary: Research indicates that ORF1p can bind with lead ions, with a model peptide showing similarity in structure and preorganization for lead ion binding. These findings suggest that exposure to heavy metals may directly impact ORF1p structure, influencing LINE1 retrotransposition frequency.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Inorganic & Nuclear
Tyler B. J. Pinter, Catherine S. Ervin, Aniruddha Deb, James E. Penner-Hahn, Vincent L. Pecoraro
Summary: The protein ORF1p of long interspersed nuclear elements-1 (L1) can bind copper ions in a pH-dependent manner, potentially affecting its structure and biological activity.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
Nicholas A. Miller, April K. Kaneshiro, Arkaprabha Konar, Roberto Alonso-Mori, Alexander Britz, Aniruddha Deb, James M. Glownia, Jake D. Koralek, Leena Mallik, Joseph H. Meadows, Lindsay B. Michocki, Tim B. van Driel, Markos Koutmos, S. Padmanabhan, Montserrat Elias-Arnanz, Kevin J. Kubarych, E. Neil G. Marsh, James E. Penner-Hahn, Roseanne J. Sension
JOURNAL OF PHYSICAL CHEMISTRY B
(2020)
Article
Chemistry, Inorganic & Nuclear
Yingshuo Liu, Aniruddha Deb, Kwan Yee Leung, Weixuan Nie, William S. Dean, James E. Penner-Hahn, Charles C. L. McCrory
DALTON TRANSACTIONS
(2020)