期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 53, 期 32, 页码 12655-12664出版社
AMER CHEMICAL SOC
DOI: 10.1021/ie5016238
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资金
- National Natural Science Foundation of China [51376185, 51161140331]
- National Basic Research Program of China [2012CB215304]
- Natural Science Foundation of Guangdong Province [S2013010011612]
- Creative Foundation of President of Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences [y307p21001]
ZrP with large surface, mesoporous volume, and size was prepared. Its catalytic performance was evaluated in hydrolytic hydrogenation of cellulose to sorbitol/mannitol combined with commercial Ru/C. A significantly enhanced sorbitol/mannitol yield was obtained as compared with that of the water-soluble acidic phosphates and buffer solution of potassium acid phthalate combined with the same Ru/C. The enhanced yield was attributed to the Lewis and Bronsted acid on ZrP surface improving the surface's absorption and activation for cellulose and accelerating the rate-determined hydrolysis step. The maximal sorbitol/mannitol yield of 63% and 81% could be obtained by using microcrystalline and ball milling cellulose as the feedstock, respectively. The ZrP combined with Ru/C was adaptable to the high concentrated cellulose and obtained 5.8 wt % of sorbitol/mannitol concentration. The remarkably enhanced cellulose hydrolysis by ZrP sharply decreased the use of Ru/C, which is significant for the essential application.
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