Article
Engineering, Electrical & Electronic
O. F. Goktas, N. E. Koksal, O. Kaplan, A. Yildiz
Summary: The sol-gel method was used to fabricate Al-doped ZnO (AZO) thin films on p-Si substrates with smooth surfaces and highly oriented crystal structures. The analysis revealed that the AZO/Si heterojunctions exhibited nonideal diode behavior, with the 80 nm thick AZO layer demonstrating good rectifying properties.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Chemistry, Multidisciplinary
Lena Meyniel, Cedric Boissiere, Natacha Krins, Sophie Carenco
Summary: In this study, thin films of lanthanide oxysulfide were developed that are compatible with flexible substrates and retain the robustness advantages of inorganic compounds. The films, made using a low-temperature dip coating method, maintained the optical quality of the materials. The thickness of the films could be adjusted in a wide range, and thermal treatment was optimized to remove organic ligands while preserving the integrity of the nanoparticles.
Article
Chemistry, Physical
Huihuang Xu, Hua Hao, Yanjiang Xie, Xin Wang, Jianlu Geng, Minghe Cao, Zhonghua Yao, Hanxing Liu
Summary: Lead-free BaZr0.25Ti0.75O3 films grown via a sol-gel method on Pt/Ti/SiO2/Si substrates exhibit good microstructure and energy storage performance, with moderate polarization and high breakdown strength, as well as excellent temperature stability.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Carlos E. Caballero-Guerecaa, M. R. Alfaro Cruza, E. Luevano-Hipolitoa, Leticia M. Torres-Martinez
Summary: Highly transparent ZnO films were successfully deposited on glass substrates using the sol-gel technique. The quality of the films was influenced by the concentration of zinc in the precursor solution and the annealing temperature. The films showed good crystallinity and preferential orientation, and exhibited high transmittance of over 90%.
SURFACES AND INTERFACES
(2023)
Article
Materials Science, Ceramics
Angel de Jesus Morales-Ramirez, Margarita Garcia-Hernandez, Maria Luz Carrera-Jota, Paulina Garnica-Chavez, Brenely Gonzalez-Penguelly, Aristeo Garrido-Hernandez
Summary: Lu2Si2O7:Eu3+ thin films were prepared using sol-gel methods and dip coating, and exhibited a monoclinic structure with preferential orientation along a specific direction after heat treatment. The films showed strong emission from Eu3+ ions, with the optical yield and decay time increasing with the SiO2 content.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Physical
Cheng-You Li, Tsung-Hsien Hsu, Cheng-Liang Huang
Summary: Amorphous Ce2Ti2O7 (CTO) thin films were prepared on an ITO/glass substrate using the sol-gel method, and the effects of various factors on the resistance-switching characteristics of the device were studied. It was observed that diffusion of Al and self-formed AlOx at the Al/CTO interface enhance the performance of the device. By inserting an AlOx layer at the CTO/ITO interface, the RS properties of the device can be optimized, making it a promising candidate for RRAM applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Boying Wang, Hao Wang, Jiantao Wang, Chaolong Li, Feng Wang, Chunli Diao, Haiwu Zheng
Summary: In this study, lead-free 0.8STO-0.2BFO thin films with coexisting amorphous and nanocrystalline structure were prepared by a sol-gel method. By adjusting the heat-treatment temperature to form polar-nano regions, the energy storage density of the films was increased. The optimized 0.8STO-0.2BFO film exhibited excellent energy storage properties with high discharge energy storage density, temperature and frequency stability, as well as fatigue endurance.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Ceramics
Renzhong Xue, Liuyang Zhao, Siyuan Chen, Hongxuan Chen, Mengru Cui, Xintao Bai, Tao Li, Dewei Liu, Haiyang Dai
Summary: The effects of A-site transition from Ca2+ to Cd2+ on the microstructure, morphology, and electrical properties of Ca(1-x)CdxCu(3)Ti(4)O(12) thin films were investigated. The films exhibited smooth and compact surfaces without cracks. The transition from Ca2+ to Cd2+ resulted in changes in grain size and electrical properties. In particular, the simultaneous occupancy of A sites by Ca2+ and Cd2+ improved the dielectric and nonlinear properties of Ca1-xCdxCu3Ti4O12 films.
CERAMICS INTERNATIONAL
(2023)
Article
Nanoscience & Nanotechnology
Maximiliano Jesus Jara Fornerod, Alberto Alvarez-Fernandez, Eric R. Williams, Maximilian W. A. Skoda, Beatriz Prieto-Simon, Nicolas H. Voelcker, Morgan Stefik, Marc-Olivier Coppens, Stefan Guldin
Summary: Mesoporous thin films are widely used for their high surface area and efficient mass and charge transport properties. A two-step calcination process can reduce film contraction and enhance structural control, resulting in mesoporous films with higher porosity and larger pores. These films exhibit favorable characteristics for mass transport of large molecules.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
K. K. Purushothaman, G. Muralidharan, S. Vijayakumar
Summary: WO3 films were prepared via sol-gel dip coating method and their properties were studied. The films exhibited 74% transmission on glass substrate, with a thickness of about 260 nm and a smooth surface. They were used to develop complementary electrochromic smart windows in conjunction with NiO and Ni0.95Co0.05O.
Article
Materials Science, Ceramics
Hong Ye, Manabu Hagiwara, Shinobu Fujihara
Summary: Meso- and macro-porous Y2WO6:Eu3+ phosphor thin films were successfully fabricated on silica glass substrates using a Pechini-type sol-gel dip-coating method. The choice of alcohol solvents and the amount of ethylene glycol were identified as major factors affecting the size and shape of pores in the thin films. Thin films with macropores showed decreased transmittance for visible light, but enhanced red photoluminescence of Eu3+ ions, particularly on the surface, due to a synergy of increased multiple scattering and suppressed internal reflection of emission light.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2021)
Article
Chemistry, Physical
Kumud Choudhary, Richa Saini, Gaurav K. Upadhyay, L. P. Purohit
Summary: Yttrium doped ZnO:CdO nanocomposite thin films were prepared and studied for CO2 gas sensing. The YZC2 sample showed promising gas sensing performance and suitable for CO2 gas sensing application. Characterization of the films was conducted using XRD, FE-SEM, and UV-Vis spectroscopy to analyze their structural, surface, and optical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Ceramics
Chao Yin, Tiandong Zhang, Bowen Zhang, Changhai Zhang, Qingguo Chi
Summary: In this study, antiferroelectric PbZrO3 films with excellent energy storage properties were prepared and systematically studied on different substrates using the sol-gel process. The results showed that the prepared M-LNO-PZO thin film exhibited high energy storage density and charge-discharge efficiency, as well as good stability under a wide range of working temperatures.
CERAMICS INTERNATIONAL
(2022)
Review
Chemistry, Physical
Matteo Poddighe, Plinio Innocenzi
Summary: The fabrication of hydrophobic thin films from a liquid phase is a widely discussed topic with critical technological issues. The interest in producing hydrophobic surfaces is growing steadily due to their vast applications in various industrial fields. The synthesis of hydrophobic films through sol-gel processing allows for multifunctional design and fine-tuning of properties, leading to significant advancements in the field.
Article
Materials Science, Ceramics
M. Chakraborty, E. S. Kadir, R. N. Gayen
Summary: By varying the graphene oxide (GO) content, the modification of UV photo-response characteristics in transparent titanium dioxide-graphene oxide (TiO2-GO) nanocomposite thin films was studied. The presence of GO improves the optical band gap of TiO2 without affecting its transparency. The fabricated metal-semiconductor (MS) Schottky junctions with TiO2-GO nanocomposite thin films show rectifying behavior and improved UV response characteristics.
CERAMICS INTERNATIONAL
(2023)
Article
Multidisciplinary Sciences
Meneka Banik, Shaili Sett, Chirodeep Bakli, Arup Kumar Raychaudhuri, Suman Chakraborty, Rabibrata Mukherjee
Summary: Experimental and simulation studies have revealed the influence of substrate wettability on the orientation of Janus particles during self-assembly. The particles show specific orientation on hydrophilic and hydrophobic substrates, while exhibiting random arrangement on neutral substrates.
SCIENTIFIC REPORTS
(2021)
Article
Polymer Science
Anuja Das, Rabibrata Mukherjee
Summary: The research found that ultrathin polymer films exhibit random holes, threadlike morphology, and an array of droplets, with the characteristics of these dewetted droplets modulated by the addition of nanoparticles. Additionally, the dewetting process of the films is influenced differently by thermal annealing or solvent vapor exposure, with much faster dynamics observed in solvent vapor-induced dewetting.
Article
Polymer Science
Nandini Bhandaru, Rabibrata Mukherjee
Summary: In this study, dewetting of a thin polymer bilayer consisting of a stacked polystyrene (PS) film on top of a topographically patterned poly(methyl methacrylate) (PMMA) bottom layer on a nonwettable substrate results in a myriad of partially or fully ordered patterns. The local thicknesses of the thinnest parts of both layers collectively influence the evolution pathway and extent of ordering in the final dewetted features. Different values of h(R-PMMA) and h(T-PS) lead to different morphologies of ordered structures during the dewetting process.
Article
Chemistry, Physical
Palash Dhara, Rabibrata Mukherjee
Summary: This paper reports on the morphology, phase separation, instability, and dewetting of Polymer dispersed liquid crystal (PDLC) thin film comprising nematic liquid crystal, 4-n-pentyl-4'-cyanobiphenyl (5CB), and Polystyrene (PS). It is found that the thickness and composition of the film play a crucial role in their properties, and topographically patterned substrates can help align the phase-separated LC domains.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Multidisciplinary
Saumyadwip Bandyopadhyay, Somnath Santra, Sankha Shuvra Das, Rabibrata Mukherjee, Suman Chakraborty
Summary: Liquid-infused slippery surfaces have superior self-healing and liquid repelling characteristics compared to structural superhydrophobic surfaces. The development of a biodegradable, recyclable, and economically viable material in the form of paper matrix for fabricating liquid-infused slippery interfaces shows great potential for various applications, especially in anti-icing properties and microfluidics. These results open up new possibilities for high-throughput paper-based substrates in a wide range of applications.
Article
Polymer Science
Anuja Das, Arka Bikash Dey, Gouranga Manna, Milan K. Sanyal, Rabibrata Mukherjee
Summary: This study demonstrates that an unstable thin polymer bilayer can be completely stabilized by adding gold nanoparticles only to the top layer. X-ray studies reveal that the nanoparticles migrate to the film-substrate interface after thermal annealing, providing stability to the bottom layer. The novelty of this technique lies in achieving complete stabilization of the bilayer by adding particles to only one layer.
Article
Polymer Science
Akanksha Rastogi, Sumita Sahoo, Tapas Kumar Bandyopadhyay, Rabibrata Mukherjee, Rintu Banerjee
Summary: This study investigates the kinetics and morphology of bacterial cellulose production by Leifsonia soli. The cellulose layer formation was observed to increase until the 7th day of incubation. X-ray diffraction analysis confirmed the semi crystalline nature of cellulose and identified its structure as allomorphs of I alpha and I beta. The study provides insights into the mechanism of cellulose formation and predicts the maximum cellulose synthesis.
Article
Chemistry, Physical
Sumita Sahoo, Rabibrata Mukherjee
Summary: This study reports the evaporation dynamics of water droplets over liquid infused slippery surfaces with high viscosity silicone oil. The results show that the surface topography and viscosity of the oil layer have effects on the morphological evolution during the evaporation process of water droplets.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Chemistry, Multidisciplinary
Pichkari Saikiran, Mayuri Dhole, Nandini Bhandaru
Summary: Due to the increased industrial oily wastewater, developing a successful oil/water separation mechanism is a ubiquitous challenge. In this work, we successfully constructed a durable GO*-coated wire mesh with selective response towards oil and water based on the difference in surface tension. The GO*-coated mesh showed promising long-term durability and retained a significant level of underwater oleophobicity even after 60 days of continuous immersion in water.
NANOSCALE ADVANCES
(2023)
Article
Chemistry, Multidisciplinary
Saumyadwip Bandyopadhyay, Anshika Shristi, Vinit Kumawat, Ayan Gope, Anurup Mukhopadhyay, Suman Chakraborty, Rabibrata Mukherjee
Summary: Rose petals exhibit sticky and superhydrophobic wetting properties. Short time wetting on rose petals of different colors remains unaddressed in existing studies. This paper compares drop impact studies on replicas of yellow and red rose petals, as well as lotus leaf. Results show that the initial impact outcome differs depending on the kinetic energy of the impacting drop, with the droplet always pinning on the red rose petal replica. A comprehensive regime phase map is presented based on experimental findings, along with a scaling analysis to understand the effect of topographical parameters on wetting regime transition.
Article
Biochemistry & Molecular Biology
Anurup Mukhopadhyay, Ayan Gope, Kabita Choudhury, Jyotirmoy Chatterjee, Rabibrata Mukherjee
Summary: This paper reports the fabrication of a porous, biomimetically patterned silk fibroin scaffold loaded with ampicillin for controlled release of the drug. The scaffolds with hierarchical surface patterns showed lower swelling and degradation compared to other types of scaffolds. The patterned surface exhibited broad-spectrum antibacterial efficacy and demonstrated superior properties in terms of cell adhesion and expression of specific proteins compared to other variants.
MACROMOLECULAR BIOSCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Sumita Sahoo, Rabibrata Mukherjee
Summary: We investigated the morphological evolution and pattern formation during the evaporative drying of a droplet of PMMA dissolved in tetrahydrofuran on a soft, swellable Sylgard 184 substrate. Unlike the well-known coffee ring formation on a rigid substrate, the presence of solvent penetration and swelling on the Sylgard 184 substrate led to a more complex behavior. The combination of evaporation and diffusive penetration resulted in faster solvent loss, the formation of a polymer shell, and the spreading of the three-phase contact line.
Article
Mechanics
Nilanjan Mondal, Diptesh Biswas, Rabibrata Mukherjee, Chirodeep Bakli
Summary: The dynamics of droplets on solid surfaces post-impingement is crucial for various technological applications. The article presents a simplified universal approach to predict droplet oscillation dynamics on any solid surface, considering a wide range of fluid and solid properties. A common framework is provided to characterize the short-time response of droplets based on lumped simple harmonic oscillator parameters.
Article
Chemistry, Physical
Pichkari Saikiran, D. Purnima, Nandini Bhandaru
Summary: Thin polymer films can dewet on non-wettable substrates, forming an array of droplets. This study focuses on the process of dewetting polystyrene films on patterned substrates. The findings reveal that the initial stages of dewetting follow the direction of the underlying pattern, while later stages involve coalescence of polymer threads. Furthermore, the shape and anisotropy of the dewetted droplets can be controlled by solvent vapor concentration.
Article
Chemistry, Physical
Madhumita Choudhuri, Meneka Banik, Rabibrata Mukherjee
Summary: This article presents a facile template guided approach for fabricating ordered non-close packed (NCP) arrays of colloidal particles. Soft lithography is used to replicate hexagonal close packed (HCP) arrays, obtaining topographically patterned positive and/or negative replicas. These replicas are then used as templates to spin coat smaller colloidal particles, resulting in ordered NCP arrays. The NCP arrays can be transferred onto any flat surface by UVO mediated colloidal transfer printing.