Article
Engineering, Chemical
Xingxun Li, Cunning Wang, Qingping Li, Weixin Pang, Guangjin Chen, Changyu Sun
Summary: Understanding the mechanisms of hydrate formation and dissociation through microfluidic visualization in a porous micromodel is essential for natural gas hydrate exploration. Different methane hydrate formations and dissociation behaviors were observed, with significant differences between methane-pure water and methane-brine systems. The study also highlighted the impact of multiple formation-dissociation processes on gas-liquid interfaces and subsequent hydrate behaviors.
CHEMICAL ENGINEERING SCIENCE
(2022)
Article
Engineering, Environmental
Sijia Wang, Zucheng Cheng, Qingbin Liu, Pengfei Lv, Junchen Lv, Lanlan Jiang, Yongchen Song
Summary: This study investigated the microscale mechanism of hydrate formation and dissociation, identifying different crystal structures and local reformation during the dissociation process. The findings provide insights into the phase transition of hydrates and efficiency of methane hydrate dissociation.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Thermodynamics
T. P. Adamova, A. Yu Manakov, D. S. Elistratov, A. A. Pil'nik, A. A. Chernov
Summary: This study presents experimental investigations on methane hydrate formation in aqueous foam stabilized by surfactants. The formation process starts near the chamber walls and propagates through the sample volume at approximately 1 mm/s rate. Phenomena such as foam structure deformation, subsidence of foam, and generation of polycrystalline conical conglomerates at the foam-solution boundary are described during the hydrate formation process.
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER
(2021)
Article
Thermodynamics
Chunxiao Li, Liang Yang, Daoping Liu, Ni Liu, Yingming Xie, Guomin Cui, Lixin Zhang, Ming Gao, Yugang Zhao, Juan Wang
Summary: This study finds that wet tobacco samples can promote the formation of hydrates. The wet loose biomass materials provide abundant nucleation sites and accelerate the formation rate of hydrates. In addition, wet tobacco samples exhibit higher gas uptake, which can be beneficial for the application of hydrate-based technology.
Article
Energy & Fuels
Limin Wang, Xin Zheng, Peng Xiao, Xing Huang, Bei Liu, Zhi Li, Guangjin Chen, Changyu Sun
Summary: The role of wax crystals in hydrate nucleation and growth is complex, with inhibitory effects on growth but dual effects on nucleation. The mass transfer of methane is influenced by the presence of wax crystals, whereby smaller crystals promote nucleation and larger crystals hinder mass transfer.
Article
Chemistry, Physical
Zhi Li, Bei Liu, Yinghua Gong, Guangjin Chen, Tianduo Li
Summary: In this study, the impact of wax crystal on the formation of methane hydrate was examined using molecular dynamics technique. The results showed that small wax crystals promoted the formation of hydrate while large wax crystals inhibited it. These findings contribute to a better understanding of the interaction between wax and hydrate.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Energy & Fuels
Rui Tan, Pengchao Wang, Yan He
Summary: In this study, a new horizontal biaxial stirring instrument was used to prepare cyclopentane hydrate, and computational fluid dynamics (CFD) numerical simulation was used to study the flow, pressure, and velocity fields. The results showed that the complex secondary flow promoted the mixing of cyclopentane and water, reduced the dead zone area, and decreased the risk of adherent growth of hydrate.
Article
Engineering, Marine
Haopeng Zeng, Yu Zhang, Lei Zhang, Zhaoyang Chen, Xiaosen Li
Summary: The presence of salts and sea mud affects the formation of natural gas hydrates (NGH). Low NaCl concentration and low montmorillonite content can reduce the induction time of hydrate formation, while high NaCl concentration and high montmorillonite content significantly increase the induction time. The increase in NaCl concentration enhances the inhibition of hydrate formation and reduces the final water conversion.
JOURNAL OF MARINE SCIENCE AND ENGINEERING
(2022)
Article
Energy & Fuels
Jun Duan, Qianchuan Li, Yue Fu, Shujun Chen, Yaxue Zhang, Dandan Liu
Summary: This study investigates the application of metal-organic frameworks (MOFs) in CH4 adsorption-hydration hybrid storage. It is found that the inner cavities of hydrophobic ZIF-8 can act as CH4 physisorption sites, and hydrate formation preferentially occurs in micro bulges and surface gaps. A novel approach to enhance hydrate formation by using different particle sizes of ZIF-8 is proposed based on the experimental results.
Article
Engineering, Environmental
Mirian E. Casco, Sven Gratz, Dirk Wallacher, Nico Grimm, Daniel M. Tobbens, Malina Bilo, Natascha Speil, Michael Froba, Lars Borchardt
Summary: The study investigated methane hydrate formation process in confinement through high-pressure methane sorption experiments on two wet materials with similar pore size distributions, B-PMO (hydrophobic) and MCM-41 (hydrophilic). The results showed that external water and 'core water' inside the pore were rapidly consumed in the first step to form bulk-like hydrate, while adsorbed water was slowly consumed in the second step to form less stable confined hydrates.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Zhixia Deng, Yanhong Wang, Xuemei Lang, Gang Li, Chi Yu, Shenglong Wang, Shuanshi Fan
Summary: This study visualized the formation and decomposition process of hydrate on the fluorinated graphite layer for the first time. It was found that the addition of fluorinated graphite promoted the formation of hydrate and increased gas storage capacity and rate. The optimized FG + SDS system showed excellent stability and was a promising alternative to hydrate-based SNG technology.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Geochemistry & Geophysics
David Fukuyama, Hugh C. Daigle, Michael A. Nole, Wen Song
Summary: Short-range diffusion and long-range advection are the main mechanisms for transporting methane. This study introduces a new mechanism, density-driven convection, which is driven by hydrate formation and salt exclusion in the pore water. The study demonstrates the rapid transport of aqueous methane throughout the sand layer with convection compared with diffusion.
EARTH AND PLANETARY SCIENCE LETTERS
(2023)
Article
Energy & Fuels
Xingxun Li, Ming Liu, Qingping Li, Weixin Pang, Guangjin Chen, Changyu Sun
Summary: This study investigated the formation and depressurization-induced dissociation behaviors of methane hydrate in porous media using a high-pressure transparent micro-packed bed reactor. The results revealed the effect of methane bubble dispersion on hydrate formation, observed hydrate reformation during depressurization, and demonstrated the impact of fluid extraction rate on hydrate reformation. The dissociation process of hydrate and fluid migration phenomena in the pore spaces were also visualized.
Article
Thermodynamics
Jiyue Sun, Lei Jiang, I. Ming Chou, Ngoc N. Nguyen, Anh V. Nguyen, Ying Chen, Juezhi Lin, Chuanjun Wu
Summary: This study investigated the thermodynamics and kinetics of methane hydrate formation in the presence of cetyltrimethylammonium bromide (CTAB) solutions. The cage occupancy and hydration number of the hydrates were determined, showing a range of 3.1-3.6 and 5.9-6.1, respectively. CTAB was found to have no impact on the phase equilibria of methane hydrate, and the kinetic rate constants for different CTAB solutions were also determined. Additionally, large-scale reactor experiments demonstrated the ability of CTAB to promote hydrate formation.
Article
Engineering, Environmental
Peng Zhang, Xueping Chen, Lianhai Zhang, Shuaijun Li, Wenting Chen, Qingbai Wu, Shuanshi Fan, Rui Bao, Cuicui Mu
Summary: Recent field studies have confirmed the presence of liquid water within hydrate-bearing reservoirs. However, the potential effects of liquid water migration on the formation and dissociation of gas hydrate have not been investigated. This study used brown clay as a medium for mobile liquid water and observed the effects of temperature gradients on hydrate formation and dissociation. The results showed that liquid water migration is responsible for heterogeneities and localities within the stability region of methane hydrate.
CHEMICAL ENGINEERING JOURNAL
(2023)
Review
Engineering, Chemical
Ningning Lu, Donglai Xie
INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING
(2016)
Review
Engineering, Chemical
Ningning Lu, Donglai Xie
INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING
(2016)
Article
Energy & Fuels
Ningning Lu, Fausto Gallucci, Tommaso Melchiori, Donglai Xie, Martin Van Sint Annaland
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION
(2018)
Article
Engineering, Chemical
Donglai Xie, Ang Peng, Ziliang Wang, Yajun Zhang
INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING
(2012)
Article
Chemistry, Physical
Donglai Xie, Jie Zhao, Ziliang Wang, Yajun Zhang
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2013)
Article
Chemistry, Physical
Donglai Xie, Ningning Lu, Fang Wang, Shuanshi Fan
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2013)
Article
Chemistry, Physical
Yajun Zhang, Shuimu Wu, Lian Jin, Donglai Xie
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2014)
Article
Chemistry, Physical
Ningning Lu, Donglai Xie, Fang Wang
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2014)
Article
Thermodynamics
Donglai Xie, Erato Zhang, Ruijun Li, Yajun Zhang
INTERNATIONAL JOURNAL OF LOW-CARBON TECHNOLOGIES
(2014)
Article
Environmental Sciences
Yifan Wang, Jianfeng Tang, Fei Li, Donglai Xie, Fengyuan Zuo, Xiao Yu, Yifei Xu, Jie Chen
Summary: This study employed a downwind quantification approach to directly measure the methane emissions of nine compressed natural gas fueling stations in East China. It was found that the emissions from these stations can be divided into intermittent emissions and continuous emissions.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Multidisciplinary Sciences
Yifan Wang, Jianfeng Tang, Donglai Xie, Fei Li, Ming Xue, Bo Zhao, Xiao Yu, Xiaojin Wen
Summary: Natural gas is becoming more important for China's transition to renewable sources. In this study, we measured methane emissions from five LNG fueling stations in Shandong, China and found that the emissions varied greatly among stations. The emissions were categorized into low, medium, and high grades based on measured methane concentration enhancement.
SCIENTIFIC REPORTS
(2022)
Article
Environmental Sciences
Xiangang Xu, Xinyue Zhong, Jiankai Dong, Donglai Xie, Wanlu Lu
Summary: Methane is a significant greenhouse gas and its emissions from the natural gas sector are often underestimated. This study used a mass balance approach to quantify methane emissions during the installation of natural gas meters and found a fat tail distribution in the emissions. The total methane emissions in China were substantial, with the highest emissions concentrated in the southeast. This research fills a gap in measuring methane emissions across the natural gas chain in China and provides data to support reduction targets and technologies.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Environmental Sciences
Scott P. Seymour, Donglai Xie, Hugh Z. Li, Katlyn MacKay
Summary: The methane emissions from the oil and gas industry in Canada, especially in Alberta, have been significantly underreported in the national greenhouse gas inventory. This underreporting raises uncertainty in the claimed emission reductions and poses challenges for validation. It is crucial for the government to improve the reliability and representativeness of emission data to accurately track and achieve the reduction targets.
ELEMENTA-SCIENCE OF THE ANTHROPOCENE
(2022)
Proceedings Paper
Engineering, Electrical & Electronic
Jianhui Liu, Shuanshi Fan, Donglai Xie
ADVANCES IN POWER AND ELECTRICAL ENGINEERING, PTS 1 AND 2
(2013)
Proceedings Paper
Energy & Fuels
Jianwen Ye, Donglai Xie, Zhenhua Yang, Zhiyu Cao
PROGRESS IN RENEWABLE AND SUSTAINABLE ENERGY, PTS 1 AND 2
(2013)