4.6 Article

Highly Sensitive and Selective Alcohol Sensors based on Ag-Doped In2O3 Coating

期刊

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 49, 期 8, 页码 3539-3543

出版社

AMER CHEMICAL SOC
DOI: 10.1021/ie100197b

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资金

  1. Natural Science Foundation of China [20873118]
  2. Program for New Century Excellent Talents in University [NCET-08-0665]
  3. Program for Science & Technology Innovation Talents in Universities of Henan Province [2008 HASTIT016]
  4. Henan Province Science and Technology [082102230036]
  5. Natural Science Foundation of Henan Province, China [97A158]
  6. Innovation Scientists and Technicians Troop Construction Projects of Henan Province [10410051001]

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In this paper, we describe how to synthesize Ag-doped In2O3 nano particles and fabricate highly sensitive and selective alcohol sensors by solid-state reaction treatment from In(NO3)(3)center dot 5H(2)O and AgNO3 mixtures at room temperature followed by calcination at 600 degrees C for 2 h. The samples were characterized by X-ray diffraction, scanning electronic microscopy, X-ray photoelectron spectroscopy. The diameter of the as-synthesized particle diameter is similar to 80 nm under different dosage of Ag doping. In comparison with pure In2O3 sensor, all of the Ag-doped sensors showed better sensing performance in sensitivity, selectivity and optimum operating temperature. The effects of Ag content, alcohol vapor concentration, and operating temperature on the sensing characteristics of the Ag-doped In2O3 sensors were also investigated. We found that the Ag-doped sensor containing 10.0 mol % Ag exhibited the maximum sensitivity to alcohol vapor at 150 degrees C. A possible mechanism for the influence of Ag on the alcohol-sensing properties of Ag-doped In2O3 sensors was proposed.

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