4.6 Article

Hydrogenation of vegetable oils over Pd on nanocomposite carbon catalysts

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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 47, 期 19, 页码 7219-7225

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AMER CHEMICAL SOC
DOI: 10.1021/ie800663j

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Catalytic hydrogenation of vegetable oils was studied over Pd nanocomposite carbon catalysts. The mesoporous structure of the carbon support was beneficial to achieve fast hydrogenation rates and the desired cis/trans ratio of monoenic products of edible oil hydrogenation.. The preparation procedure developed for a slurry catalyst was successfully utilized for fixed bed applications. Industrial experience of Pd/nanocomposite carbon utilization in selective hydrogenation of edible and total hydrogenation of nonedible oils is described.

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