期刊
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS
卷 46, 期 -, 页码 553-564出版社
ELSEVIER
DOI: 10.1016/j.msec.2014.10.072
关键词
Scaffold; Baghdadite; Nanoindentation; Ultrasound; Micromechanics
资金
- European Research Council (ERC) [ERC-2010-StG-257032-MICROBONE]
- Australian Research Council (ARC) [LP0991099]
- Australian Research Council [LP0991099] Funding Source: Australian Research Council
Microstructure-elasticity relations for bone tissue engineering scaffolds are key to rational biomaterial design. As a contribution thereto, we here report comprehensive length measuring, weighing, and ultrasonic tests at 0.1 MHz frequency, on porous baghdadite (Ca3ZrSi2O9) scaffolds. The resulting porosity-stiffness relations further confirm a formerly detected, micromechanically explained, general relationship for a great variety of different polycrystals, which also allows for estimating the zero-porosity case, i.e. Young modulus and Poisson ratio of pure (dense) baghdadite. These estimates were impressively confirmed by a physically and statistically independent nanoindentation campaign. comprising some 1750 indents. Consequently, we can present a remarkably complete picture of porous baghdadite elasticity across a wide range of porosities, and, thanks to the micromechanical understanding, reaching out beyond classical elasticity, towards poroelastic properties, quantifying the effect of pore pressure on the material system behavior. (C) 2014 The Authors. Published by Elsevier B.V.
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