期刊
IEEE SENSORS JOURNAL
卷 8, 期 5-6, 页码 735-742出版社
IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC
DOI: 10.1109/JSEN.2008.923179
关键词
chemical warfare agents (CWAs); DMMP; explorative data analysis; MOS devices; nanowires; thin films
资金
- European Strep [001528]
- NATO Project [982166]
This work concerns with metal oxide (MOX) gas sensors based on nanowires and thin films. We focus on chemical warfare agents (CWAs) detection to compare these materials from the functional point-of-view. We work with different chemicals including simulants for Sarin nerve agents, vescicant gases, cyanide agents, and analytes such as ethanol, acetone, ammonia, and carbon monoxide that can be produced by everyday activities causing false alarms. Explorative data analysis has been used to demonstrate the different sensing performances of nanowires and thin films. Within the chosen application, our analysis reveal that the introduction of nanowires inside the array composed by thin films can improve its sensing capability. Cyanide simulants have been detected at concentrations close to 1 ppm, lower than the Immediately Dangerous for Life and Health (IDLH) value of the respective warfare agent. Higher sensitivity has been obtained to simulants for Sarin and vescicant gases, which have been detected at concentrations close or even lower than 100 ppb. Results demonstrate the suitability of the proposed array to selectively detect CWA simulants with respect to some compounds produced by everyday activities.
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