Titan's aerosol and stratospheric ice opacities between 18 and 500 μm: Vertical and spectral characteristics from Cassini CIRS

Vertical distributions and spectral characteristics of Titan's photochemical aerosol and stratospheric ices are determined between 20 and 560 cm(-1) (500-18 mu m) from the Cassini Composite Infrared Spectrometer (CIRS). Results are obtained for latitudes of 15 degrees N, 15 degrees S, and 58 degrees S. where accurate temperature profiles can be independently determined. In addition, estimates of aerosol and ice abundances at 62 degrees N relative to those at 15 degrees S are derived. Aerosol abundances are comparable at the two latitudes, but stratospheric ices are similar to 3 times more abundant at 62 degrees N than at 15 degrees S. Generally, nitrile ice clouds (probably HCN and HC3N), as inferred from a composite emission feature at similar to 160 cm(-1), appear to be located over a narrow altitude range in the stratosphere centered at similar to 90 km. Although most abundant at high northern latitudes, these nitrile ice clouds extend down through low latitudes and into mid southern latitudes, at least as far as 58 degrees S. There is some evidence of a second ice cloud layer at similar to 60 km altitude at 58 degrees S associated with an emission feature at similar to 80 cm(-1). We speculate that the identify of this cloud may be due to C2H6 ice, which in the vapor phase is the most abundant hydrocarbon (next to CH4) in the stratosphere of Titan. Unlike the highly restricted range of altitudes (50-100 km) associated with organic condensate clouds, Titan's photochemical aerosol appears to be well-mixed from the surface to the top of the stratosphere near an altitude of 300 km, and the spectral shape does not appear to change between 15 degrees N and 58 degrees S latitude. The ratio of aerosol-to-gas scale heights range from 1.3-2.4 at about 160 km to 1.1-1.4 at 300 km, although there is considerable variability with latitude. The aerosol exhibits a very broad emission feature peaking at similar to 140 cm-1. Due to its extreme breadth and low wavenumber, we speculate that this feature may be caused by low-energy vibrations of two-dimensional lattice structures of large molecules. Examples of such molecules include polycyclic aromatic hydrocarbons (PAHs) and nitrogenated aromatics. Finally, volume extinction coefficients N chi(E) derived from 15 degrees S CIRS data at a wavelength of lambda = 62.5 mu m are compared with those derived from the 10 degrees S Huygens Descent Imager/Spectral Radiometer (DISR) data at 1.583 mu m. This comparison yields volume extinction coefficient ratios N chi(E)(1.583 mu m)/N chi(E)(62.5 mu m) of roughly 70 and 20, respectively, for Titan's aerosol and stratospheric ices. The inferred particle cross-section ratios chi(E)(1.583 mu m)/chi(E)(62.5 mu m) appear to be consistent with sub-micron size aerosol particles, and effective radii of only a few microns for stratospheric ice cloud particles. Published by Elsevier Inc.