Leaching of silica from vanadium-bearing steel slag in sodium hydroxide solution

The work aims to selectively extract silica from vanadium-bearing steel slag by a leaching process. The effects of the particle size, the ratio of solid to liquid, the concentration of sodium hydroxide solution and the leaching temperature on the leaching behavior of silica from vanadium-bearing steel slag were investigated. The leaching kinetics of silica from vanadium-bearing steel slag in 30-50% w/w NaOH solutions was studied at 240 degrees C and the shrinking-core model was established to express the leaching kinetics of silica. The data showed that the leaching rate was controlled by the chemical reaction on the system interface and the activation energy for the process was found to be 36.4 kJ mol(-1). By the leaching process, the majority of silica could be removed effectively from the vanadium-bearing steel slag and a residue with a low SiO(2) content of 4.28% and a high V(2)O(5) content of 11.15% was obtained. Under these conditions there was partial dissolution of Al and slight dissolution of Cr, Mn and Ti. (C) 2010 Elsevier B.V. All rights reserved.