期刊
HEMIJSKA INDUSTRIJA
卷 66, 期 6, 页码 795-804出版社
ASSOC CHEMISTS & CHEMICAL ENGINEERS OF SERBIA
DOI: 10.2298/HEMIND121002112M
关键词
poly(4-vinylpyridine-co-divinylbenzene) macroporous copolymer; Cu(II), Co(II) and Cr(VI) ions sorption; kinetic models
资金
- Ministry of Education, Science and Technological Development of the Republic of Serbia [III 43009]
Commercial macroporous poly(4-vinylpyridine-co-divinylbenzene) [P4VPD], known as Reillex-425, was characterized by mercury porosimetry, nitrogen physisorption, Fourier transformed infrared (FTIR) spectroscopy and elemental analysis. Sorption rates of P4VPD for Cu(II), Co(II) and Cr(VI) ions were determined in static non-competitive experiments, at room temperature (298 K). Rapid sorption was observed, especially for Co(II), with half time, t(1/2), of 1.5 min and high experimental maximal capacity, Q(max), of 3.08 mmol g(-1). Four kinetic models (pseudo-first and pseudo-second order model, intraparticle diffusion and Boyd model) were used for analyzing metal sorption by P4VPD. Metal ions sorption is well represented by the pseudo-second-order model, with definite influence of pore and film diffusion on sorption rates.
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