期刊
HELVETICA CHIMICA ACTA
卷 95, 期 12, 页码 2446-2459出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/hlca.201200490
关键词
Amino acids; Glycine; Peptides; X-Ray crystallography
The synthesis, optical resolution, determination of absolute configuration and conformational preference, and spectroscopic characteristics of terminally protected (blocked) derivatives and short peptides of 2-amino-1,2,3,6-tetrahydro-6-oxocyclopenta[c]fluorene-2-carboxylic acid (FlAib), a novel, rigid, chiral, cyclized Ca,a-disubstituted glycine are described.
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