期刊
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
卷 113, 期 -, 页码 1266-1272出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.ijbiomac.2018.03.048
关键词
Oil palm fronds; Organosolv lignin; Glyoxal; Wood adhesive
资金
- Universiti Sains Malaysia through USM Short Term Research Grants [304/PKIMIA/6313216]
- USM Bridging Grants [304/PKIMIA/6316041]
- Ministry of High Education (MOHE) of Malaysia
Lignocellulosic materials can significantly contribute to the development of eco-friendly wood adhesives. In this work, glyoxal-phenolic resins for plywood were prepared using organosolv lignin, which was isolated from black liquor recovered from organosolv pulping of oil palm fronds (OPF) and considered to be an alternative to phenol. Glyoxal, which is a dialdehyde obtained from several natural resources, was used as substitute for formaldehyde. The structure of organosolv lignin and the resins were characterized by FTIR and NMR, and for thermal stability by TGA and DSC. The resins were further studied for their viscosity, pH, solids content and gel times. The resins performance as wood adhesive was further established from mechanical test in terms of tensile strength and modulus of elasticity (MOE) to obtain the optimum ratios of organosolv lignin, which replaces phenol in organosolv lignin phenol glyoxal (OLPG) resins. The adhesive composition having 50% (w/w) of phenol substituted by organosolv lignin, termed as 50% OLPG showed highest adhesive strength compared to phenol formaldehyde (PF) commercial adhesive. (C) 2018 Elsevier B.V. All rights reserved.
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