Large changes in hydricity as a function of charge and not metal in (PNP)M–H (de)hydrogenation catalysts that undergo metal–ligand cooperativity

Thermochemical Studies of Nickel Hydride Complexes with Cationic Ligands in Aqueous and Organic Solvents

(2022) Andrew D. Cypcar et al.   ORGANOMETALLICS

Temperature and Solvent Effects on H2 Splitting and Hydricity: Ramifications on CO2 Hydrogenation by a Rhenium Pincer Catalyst

(2021) Jenny Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Role of Ligand-Bound CO2 in the Hydrogenation of CO2 to Formate with a (PNP)Mn Catalyst

(2021) Kevin Schlenker et al.   ACS Catalysis

Understanding the Reactivity and Decomposition of a Highly Active Iron Pincer Catalyst for Hydrogenation and Dehydrogenation Reactions

(2021) Julia B. Curley et al.   ACS Catalysis

Cobalt-Group 13 Complexes Catalyze CO2 Hydrogenation via a Co(−I)/Co(I) Redox Cycle

(2020) Matthew V. Vollmer et al.   ACS Catalysis

Minireview on Bio-Oil Upgrading via Electrocatalytic Hydrogenation: Connecting Biofuel Production with Renewable Power

(2020) Chun Ho Lam et al.   ENERGY & FUELS

Enhanced Hydrogenation of Carbon Dioxide to Methanol by a Ruthenium Complex with a Charged Outer-Coordination Sphere

(2020) Jeremy D. Erickson et al.   ACS Catalysis

Systematic Trends in the Electrochemical Properties of Transition Metal Hydride Complexes Discovered by Using the Ligand Acidity Constant Equation

(2020) Benjamin E. Rennie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toward Combined Carbon Capture and Recycling: Addition of an Amine Alters Product Selectivity from CO to Formic Acid in Manganese Catalyzed Reduction of CO2

(2020) Moumita Bhattacharya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Coupling of Alcohols and Amines to Generate Aldimines and H2 by a Pincer Manganese Catalyst

(2019) Judit Masdemont et al.   ACS Catalysis

Oxidative Addition of Dihydrogen, Boron Compounds, and Aryl Halides to a Cobalt(I) Cation Supported by a Strong-Field Pincer Ligand

(2019) Stephan M. Rummelt et al.   ORGANOMETALLICS

Parallels between Metal-Ligand Cooperativity and Frustrated Lewis Pairs

(2019) Evi R. M. Habraken et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Manganese Catalyzed Hydrogenation of Carbamates and Urea Derivatives

(2019) Uttam Kumar Das et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of Hydride Transfer to Imines from a Highly Active and Chemoselective Manganate Catalyst

(2019) Frederik Freitag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thermodynamic Analysis of Metal–Ligand Cooperativity of PNP Ru Complexes: Implications for CO2 Hydrogenation to Methanol and Catalyst Inhibition

(2019) Cheryl L. Mathis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thermodynamic Hydricity across Solvents: Subtle Electronic Effects and Striking Ligation Effects in Iridium Hydrides

(2019) Kelsey R. Brereton et al.   ORGANOMETALLICS

Reversible and Selective CO2 to HCO2 − Electrocatalysis near the Thermodynamic Potential

(2019) Drew W. Cunningham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isoelectronic Manganese and Iron Hydrogenation/Dehydrogenation Catalysts: Similarities and Divergences

(2018) Nikolaus Gorgas et al.   ACCOUNTS OF CHEMICAL RESEARCH

From Ruthenium to Iron and Manganese-A Mechanistic View on Challenges and Design Principles of Base-Metal Hydrogenation Catalysts

(2018) Thomas Zell et al.   ChemCatChem

Catalytic (de)hydrogenation promoted by non-precious metals – Co, Fe and Mn: recent advances in an emerging field

(2018) Georgy A. Filonenko et al.   CHEMICAL SOCIETY REVIEWS

Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier

(2018) Amit Kumar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Acceleration of CO2 insertion into metal hydrides: ligand, Lewis acid, and solvent effects on reaction kinetics

(2018) Jessica E. Heimann et al.   Chemical Science

Hydricity of Transition-Metal Hydrides: Thermodynamic Considerations for CO2 Reduction

(2018) Kate M. Waldie et al.   ACS Catalysis

Manganese Catalyzed Hydrogenation of Organic Carbonates to Methanol and Alcohols

(2018) Amit Kumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation

(2018) You-Quan Zou et al.   ACS Catalysis

First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands

(2018) Lukas Alig et al.   CHEMICAL REVIEWS

Switching between Stepwise and Concerted Proton-Coupled Electron Transfer Pathways in Tungsten Hydride Activation

(2018) Tao Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous Catalysis by Cobalt and Manganese Pincer Complexes

(2018) Arup Mukherjee et al.   ACS Catalysis

Why Does Alkylation of the N–H Functionality within M/NH Bifunctional Noyori-Type Catalysts Lead to Turnover?

(2017) Pavel A. Dub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding the Relationship Between Kinetics and Thermodynamics in CO2 Hydrogenation Catalysis

(2017) Matthew S. Jeletic et al.   ACS Catalysis

Metal–Ligand Bifunctional Catalysis: The “Accepted” Mechanism, the Issue of Concertedness, and the Function of the Ligand in Catalytic Cycles Involving Hydrogen Atoms

(2017) Pavel A. Dub et al.   ACS Catalysis

Liquid Organic Hydrogen Carriers (LOHCs): Toward a Hydrogen-free Hydrogen Economy

(2016) Patrick Preuster et al.   ACCOUNTS OF CHEMICAL RESEARCH

Unprecedented iron-catalyzed selective hydrogenation of activated amides to amines and alcohols

(2016) Jai Anand Garg et al.   CHEMICAL COMMUNICATIONS

Thermodynamic Hydricity of Transition Metal Hydrides

(2016) Eric S. Wiedner et al.   CHEMICAL REVIEWS

Toward Rational Design of 3d Transition Metal Catalysts for CO2 Hydrogenation Based on Insights into Hydricity-Controlled Rate-Determining Steps

(2016) Bhaskar Mondal et al.   INORGANIC CHEMISTRY

Experimental and Theoretical Study of CO2 Insertion into Ruthenium Hydride Complexes

(2016) Srinivasan Ramakrishnan et al.   INORGANIC CHEMISTRY

Experimental Basicities of Superbasic Phosphonium Ylides and Phosphazenes

(2016) Jaan Saame et al.   JOURNAL OF ORGANIC CHEMISTRY

Aqueous Hydricity of Late Metal Catalysts as a Continuum Tuned by Ligands and the Medium

(2016) Catherine L. Pitman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unravelling the Mechanism of Basic Aqueous Methanol Dehydrogenation Catalyzed by Ru–PNP Pincer Complexes

(2016) Elisabetta Alberico et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Ligand Modifications with Pendent OH Groups Dramatically Impact the Activity and Selectivity of Ruthenium Catalysts for Transfer Hydrogenation: The Importance of Alkali Metals

(2016) Cameron M. Moore et al.   ACS Catalysis

Metal-Ligand Cooperation

(2015) Julia R. Khusnutdinova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction

(2015) Wan-Hui Wang et al.   CHEMICAL REVIEWS

Control in the Rate-Determining Step Provides a Promising Strategy To Develop New Catalysts for CO2 Hydrogenation: A Local Pair Natural Orbital Coupled Cluster Theory Study

(2015) Bhaskar Mondal et al.   INORGANIC CHEMISTRY

Solvation Effects on Transition Metal Hydricity

(2015) Charlene Tsay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Incorporation of Pendant Bases into Rh(diphosphine)2 Complexes: Synthesis, Thermodynamic Studies, And Catalytic CO2 Hydrogenation Activity of [Rh(P2N2)2]+ Complexes

(2015) Alyssia M. Lilio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational Mechanistic Studies on Reactions of Transition Metal Complexes with Noninnocent Pincer Ligands: Aromatization–Dearomatization or Not

(2015) Haixia Li et al.   ACS Catalysis

Bond Activation and Catalysis by Ruthenium Pincer Complexes

(2014) Chidambaram Gunanathan et al.   CHEMICAL REVIEWS

A DFT Study: Why Do [Ni(PR2NR′2)2]2+ Complexes Facilitate the Electrocatalytic Oxidation of Formate?

(2014) Liqin Xue et al.   INORGANIC CHEMISTRY

Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes

(2014) Margaret L. Scheuermann et al.   INORGANIC CHEMISTRY

Development of Molecular Electrocatalysts for Energy Storage

(2014) Daniel L. DuBois   INORGANIC CHEMISTRY

Four-Coordinate Cobalt Pincer Complexes: Electronic Structure Studies and Ligand Modification by Homolytic and Heterolytic Pathways

(2014) Scott P. Semproni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Estimating the Acidity of Transition Metal Hydride and Dihydrogen Complexes by Adding Ligand Acidity Constants

(2014) Robert H. Morris   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal loss of an H radical by a cobalt complex via metal–ligand cooperation

(2013) Eugene Khaskin et al.   CHEMICAL COMMUNICATIONS

Efficient Hydrogen Liberation from Formic Acid Catalyzed by a Well-Defined Iron Pincer Complex under Mild Conditions

(2013) Thomas Zell et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cp*Co(III) Catalysts with Proton-Responsive Ligands for Carbon Dioxide Hydrogenation in Aqueous Media

(2013) Yosra M. Badiei et al.   INORGANIC CHEMISTRY

Base-Catalyzed Bifunctional Addition to Amides and Imides at Low Temperature. A New Pathway for Carbonyl Hydrogenation

(2013) Jeremy M. John et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Two Pathways for Electrocatalytic Oxidation of Hydrogen by a Nickel Bis(diphosphine) Complex with Pendant Amines in the Second Coordination Sphere

(2013) Jenny Y. Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Earth-abundant hydrogen evolution electrocatalysts

(2013) James R. McKone et al.   Chemical Science

Catalytic CO2 Hydrogenation to Formate by a Ruthenium Pincer Complex

(2013) Chelsea A. Huff et al.   ACS Catalysis

Formate oxidation via β-deprotonation in [Ni(PR2NR′2)2(CH3CN)]2+ complexes

(2012) Candace S. Seu et al.   Energy & Environmental Science

Thermodynamic and Kinetic Hydricity of Ruthenium(II) Hydride Complexes

(2012) Yasuo Matsubara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[Ni(PMe2NPh2)2](BF4)2 as an Electrocatalyst for H2 Production

(2012) Stefan Wiese et al.   ACS Catalysis

Efficient Hydrogenation of Ketones Catalyzed by an Iron Pincer Complex

(2011) Robert Langer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Low-Pressure Hydrogenation of Carbon Dioxide Catalyzed by an Iron Pincer Complex Exhibiting Noble Metal Activity

(2011) Robert Langer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Incorporating Peptides in the Outer-Coordination Sphere of Bioinspired Electrocatalysts for Hydrogen Production

(2011) Avijita Jain et al.   INORGANIC CHEMISTRY

Studies of a Series of [Ni(PR2NPh2)2(CH3CN)]2+Complexes as Electrocatalysts for H2Production: Substituent Variation at the Phosphorus Atom of the P2N2Ligand

(2011) Uriah J. Kilgore et al.   INORGANIC CHEMISTRY

Electrocatalytic Oxidation of Formate by [Ni(PR2NR′2)2(CH3CN)]2+Complexes

(2011) Brandon R. Galan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

(2010) Jeffrey J. Warren et al.   CHEMICAL REVIEWS

Thermodynamic Studies of [H2Rh(diphosphine)2]+and [HRh(diphosphine)2(CH3CN)]2+Complexes in Acetonitrile

(2010) Aaron D. Wilson et al.   INORGANIC CHEMISTRY

N−H Activation of Amines and Ammonia by Ru via Metal−Ligand Cooperation

(2010) Eugene Khaskin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY