Cobalt(I)-Catalyzed Transformation of Si–H Bonds: H/D Exchange in Hydrosilanes and Hydrosilylation of Olefins

Structural and Electronic Properties of Boranes Containing Boron‐Chalcogen Multiple Bonds and Stabilized by Amido Imidazoline‐2‐imine Ligands

(2022) Juan Pablo Martínez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal Halide Exchange in Benzylborane NHC‐Adducts: The Effect of Backbone Alkylation in the N ‐Heterocyclic Carbene

(2022) Daniela Wullschläger et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Iron-Catalyzed H/D Exchange of Primary Silanes, Secondary Silanes, and Tertiary Siloxanes

(2022) Thomas G. Linford-Wood et al.   ACS Catalysis

Reactions of a Four‐Membered Borete with Carbon, Silicon, and Gallium Donor Ligands: Fused and Spiro‐Type Boracycles

(2022) Zeynep Güven et al.   CHEMISTRY-A EUROPEAN JOURNAL

[P, C] Chelate Cobalt(I)-Catalyzed Distinct Selective Hydrosilylation of Alkenes under Mild Conditions

(2022) Wenjing Yang et al.   ORGANOMETALLICS

Reductive Al−B σ‐Bond Formation in Alumaboranes: Facile Scission of Polar Multiple Bonds

(2022) Zeynep Güven et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of silyl cobalt hydrides and their catalytic activity on hydrosilylation of alkenes

(2022) Haiquan Yang et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Selectivity Reverse of Hydrosilylation of Aryl Alkenes Realized by Pyridine N-Oxide with [PSiP] Pincer Cobalt(III) Hydride as Catalyst

(2021) Yanhong Dong et al.   INORGANIC CHEMISTRY

Nickel-Catalyzed Hydrosilylation of Terminal Alkenes with Primary Silanes via Electrophilic Silicon–Hydrogen Bond Activation

(2021) Xiaoyu Wu et al.   ORGANIC LETTERS

[P,C]-Chelate Cobalt(III) Hydride Catalyzed Hydrosilylation of Alkenes

(2021) Wenjing Yang et al.   ORGANOMETALLICS

Implication of a Silyl Cobalt Dihydride Complex as a Useful Catalyst for the Hydrosilylation of Imines

(2021) Cassandre C. Bories et al.   ACS Catalysis

Mechanistic insights into the chemo‐selective dehydrogenative silylation of alkenes catalyzed by bis(imino)pyridine cobalt complex from DFT computations

(2020) Haijun Jiao et al.   ChemCatChem

Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes

(2020) Longyang Dian et al.   ORGANIC LETTERS

Mechanistic Study of Alkene Hydrosilylation Catalyzed by a β-Dialdiminate Cobalt(I) Complex

(2020) Daniel Kim et al.   ORGANOMETALLICS

Superseding β‐Diketiminato Ligands: An Amido Imidazoline‐2‐Imine Ligand Stabilizes the Exhaustive Series of B=X Boranes (X=O, S, Se, Te)

(2020) Hadi Dolati et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Non-classical hydrosilane mediated reductions promoted by transition metal complexes

(2019) Manuel Iglesias et al.   COORDINATION CHEMISTRY REVIEWS

N-Heterocyclic Carbene Adducts of Alkynyl Functionalized 1,3,2-Dithioborolanes

(2019) Richard Böser et al.   MOLECULES

Benzyl Borane NHC Adducts: Beyond B−C Bond Scission

(2019) Richard Böser et al.   CHEMISTRY-A EUROPEAN JOURNAL

Two π‐Electrons Make the Difference: From BODIPY to BODIIM Switchable Fluorescent Dyes

(2019) René Frank et al.   CHEMISTRY-A EUROPEAN JOURNAL

Proximity Enforced Agostic Interactions Involving Closed-Shell Coinage Metal Ions

(2019) Emanuel Hupf et al.   INORGANIC CHEMISTRY

Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation

(2018) Jing Zhu et al.   ORGANIC LETTERS

Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

(2018) Jennifer V. Obligacion et al.   Nature Reviews Chemistry

Fe and Co Complexes of Rigidly Planar Phosphino-Quinoline-Pyridine Ligands for Catalytic Hydrosilylation and Dehydrogenative Silylation

(2018) Debashis Basu et al.   ORGANOMETALLICS

Cobalt(0) and Iron(0) Isocyanides as Catalysts for Alkene Hydrosilylation with Hydrosiloxanes

(2018) Atsushi Sanagawa et al.   ORGANOMETALLICS

Distinct Catalytic Performance of Cobalt(I)–N-Heterocyclic Carbene Complexes in Promoting the Reaction of Alkene with Diphenylsilane: Selective 2,1-Hydrosilylation, 1,2-Hydrosilylation, and Hydrogenation of Alkene

(2018) Yafei Gao et al.   ACS Catalysis

Cobalt Catalysts for Alkene Hydrosilylation under Aerobic Conditions without Dry Solvents or Additives

(2018) Silvia Gutiérrez-Tarriño et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Highly Enantioselective Cobalt-Catalyzed Hydrosilylation of Alkenes

(2017) Biao Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes

(2017) Yang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Completing the series of boron-nucleophilic cyanoborates: boryl anions of type NHC–B(CN)2−

(2017) Richard Böser et al.   Chemical Science

Control of Selectivity through Synergy between Catalysts, Silanes, and Reaction Conditions in Cobalt-Catalyzed Hydrosilylation of Dienes and Terminal Alkenes

(2017) Balaram Raya et al.   ACS Catalysis

Advances in Base-Metal-Catalyzed Alkene Hydrosilylation

(2017) Xiaoyong Du et al.   ACS Catalysis

Fifty Years of Hydrosilylation in Polymer Science: A Review of Current Trends of Low-Cost Transition-Metal and Metal-Free Catalysts, Non-Thermally Triggered Hydrosilylation Reactions, and Industrial Applications

(2017) Robin Hofmann et al.   Polymers

Reaction: Opportunities for Sustainable Catalysts

(2017) Patrick L. Holland   Chem

Base-Metal-Catalyzed Regiodivergent Alkene Hydrosilylations

(2016) Xiaoyong Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Stabilized Boryl Radicals

(2016) Miguel F. Silva Valverde et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The cobalt(II) complex of a new tridentate Schiff-base ligand as a catalyst for hydrosilylation of olefins

(2016) Adam Gorczyński et al.   CATALYSIS COMMUNICATIONS

Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes

(2016) Daisuke Noda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tetramethyldisiloxane: A Practical Organosilane Reducing Agent

(2016) Jaan Pesti et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

A Ni0(η2-(Si–H))(η2-H2) Complex That Mediates Facile H Atom Exchange between Two σ-Ligands

(2016) Bridget A. Connor et al.   ORGANOMETALLICS

Cobalt Phosphino-α-Iminopyridine-Catalyzed Hydrofunctionalization of Alkenes: Catalyst Development and Mechanistic Analysis

(2016) Wan-Yi Chu et al.   ORGANOMETALLICS

Selective Cobalt-Catalyzed Reduction of Terminal Alkenes and Alkynes Using (EtO)2Si(Me)H as a Stoichiometric Reductant

(2016) Balaram Raya et al.   ACS Catalysis

Hydrosilylation of Olefins Catalyzed by Well-Defined Cationic Aluminum Complexes: Lewis Acid versus Insertion Mechanisms

(2016) Kayla Jakobsson et al.   ACS Catalysis

Bench-Stable, Substrate-Activated Cobalt Carboxylate Pre-Catalysts for Alkene Hydrosilylation with Tertiary Silanes

(2016) Christopher H. Schuster et al.   ACS Catalysis

A Highly Chemoselective Cobalt Catalyst for the Hydrosilylation of Alkenes using Tertiary Silanes and Hydrosiloxanes

(2016) Abdulrahman D. Ibrahim et al.   ACS Catalysis

Cobalt-Catalyzed Regiodivergent Hydrosilylation of Vinylarenes and Aliphatic Alkenes: Ligand- and Silane-Dependent Regioselectivities

(2016) Chao Wang et al.   ACS Catalysis

Borane-Catalyzed Reductive α-Silylation of Conjugated Esters and Amides Leaving Carbonyl Groups Intact

(2015) Youngchan Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Hydrosilylation Polymerization by Borane Catalyst

(2015) Dong Wook Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elusive Silane-Alane Complex [SiH⋅⋅⋅Al]: Isolation, Characterization, and Multifaceted Frustrated Lewis Pair Type Catalysis

(2015) Jiawei Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst

(2015) Chi Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct and Transfer Hydrosilylation Reactions Catalyzed by Fully or Partially Fluorinated Triarylboranes: A Systematic Study

(2015) Sebastian Keess et al.   ORGANOMETALLICS

Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes

(2015) Jian Sun et al.   ACS Catalysis

Silane Deuteration Catalyzed by Ruthenium Bis(dihydrogen) Complexes or Simple Metal Salts

(2014) Katharine A. Smart et al.   ADVANCED SYNTHESIS & CATALYSIS

Si–H bond activation at {(NHC)2Ni0} leading to hydrido silyl and bis(silyl) complexes: a versatile tool for catalytic Si–H/D exchange, acceptorless dehydrogenative coupling of hydrosilanes, and hydrogenation of disilanes to hydrosilanes

(2014) David Schmidt et al.   DALTON TRANSACTIONS

Uranium(IV) Imidazolin-2-iminato Complexes: A New Class of Actinide Complexes

(2014) Isabell S. R. Karmel et al.   INORGANIC CHEMISTRY

Application of the Covalent Bond Classification Method for the Teaching of Inorganic Chemistry

(2014) Malcolm L. H. Green et al.   JOURNAL OF CHEMICAL EDUCATION

Z-Selective Alkene Isomerization by High-Spin Cobalt(II) Complexes

(2014) Chi Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis(imino)pyridine Cobalt-Catalyzed Dehydrogenative Silylation of Alkenes: Scope, Mechanism, and Origins of Selective Allylsilane Formation

(2014) Crisita Carmen Hojilla Atienza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes

(2013) Antoine Simonneau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anchoring of Silyl Donors on a N-Heterocyclic Carbene through the Cobalt-Mediated Silylation of Benzylic CH Bonds

(2013) Zhenbo Mo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition metal complexes supported by highly basic imidazolin-2-iminato and imidazolin-2-imine N-donor ligands

(2013) Xian Wu et al.   COORDINATION CHEMISTRY REVIEWS

Chemistry of Reduced Monomeric and Dimeric Cobalt Complexes Supported by a PNP Pincer Ligand

(2013) Sergio S. Rozenel et al.   INORGANIC CHEMISTRY

Synthesis and Structural Analysis of (Imido)vanadium(V) Dichloride Complexes Containing Imidazolin-2-iminato- and Imidazolidin-2-iminato Ligands, and their Use as Catalyst Precursors for Ethylene (Co)polymerization

(2013) Kotohiro Nomura et al.   INORGANIC CHEMISTRY

Mono(imidazolin-2-iminato) Titanium Complexes for Ethylene Polymerization at Low Amounts of Methylaluminoxane

(2013) Dana Shoken et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Synthesis of Silanols from Hydrosilanes and Applications

(2012) Mina Jeon et al.   ACS Catalysis

Catalytic deuteration of silanes mediated by N-heterocyclic carbene-Ir(iii) complexes

(2011) George C. Fortman et al.   CHEMICAL COMMUNICATIONS

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

(2011) Dennis Troegel et al.   COORDINATION CHEMISTRY REVIEWS

Large-scale preparation and labelling reactions of deuterated silanes

(2011) Jesús Campos et al.   JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS

A Masked Two-Coordinate Cobalt(I) Complex That Activates C–F Bonds

(2011) Thomas R. Dugan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Structure of Rare-Earth-Metal Dicarbollide Complexes with an Imidazolin-2-iminato Ligand Featuring Very Short Metal−Nitrogen Bonds

(2011) Alexandra G. Trambitas et al.   ORGANOMETALLICS

H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex

(2011) Vlad M. Iluc et al.   ORGANOMETALLICS

A Cationic Rh(III) Complex That Efficiently Catalyzes Hydrogen Isotope Exchange in Hydrosilanes

(2010) Jesús Campos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Structural Characterisation of an Isomorphous Series of Bis(imidazolin-2-imine) Metal Dichlorides Containing the First Row Transition Metals Mn, Fe, Co, Ni, Cu and Zn

(2010) Thomas Glöge et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Diamagnetic Corrections and Pascal's Constants

(2009) Gordon A. Bain et al.   JOURNAL OF CHEMICAL EDUCATION

Synthesis and Structure of PNP-Supported Iridium Silyl and Silylene Complexes: Catalytic Hydrosilation of Alkenes

(2009) Elisa Calimano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and Theoretical Investigations of Catalytic Alkyne Cross-Metathesis with Imidazolin-2-iminato Tungsten Alkylidyne Complexes

(2009) Stephan Beer et al.   ORGANOMETALLICS

Designing new free-radical reducing reagents: Theoretical study on Si–H bond dissociation energies of organic silanes

(2008) Hua-Jing Wang et al.   JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM

Alkene Hydrosilation by a Cationic Hydrogen-Substituted Iridium Silylene Complex

(2008) Elisa Calimano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(Me3Si)3SiH: Twenty Years After Its Discovery as a Radical-Based Reducing Agent

(2007) Chryssostomos Chatgilialoglu   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and reactivity of copper(i) complexes with an ethylene-bridged bis(imidazolin-2-imine) ligand

(2007) Dejan Petrovic et al.   DALTON TRANSACTIONS