The inversion of ferroelectric domains in lithium niobate by a scanning focused ultra-violet laser beam (lambda=244nm) is demonstrated. The resulting domain patterns are interrogated using piezoresponse force microscopy and by chemical etching in hydrofluoric acid. Direct ultra-violet laser poling was observed in un-doped congruent, iron doped congruent and titanium in-diffused congruent lithium niobate single crystals. A model is proposed to explain the mechanism of domain inversion. (C) 2008 Optical Society of America.
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