Dearomative triple elementalization of quinolines driven by visible light

KOtBu-Catalyzed 1,2-Silaboration of N-Heteroarenes to Access 2-Silylheterocycles: A Cooperative Model for the Regioselectivity

(2022) Eunchan Jeong et al.   ACS Catalysis

Photochemical single-step synthesis of β-amino acid derivatives from alkenes and (hetero)arenes

(2022) Guangying Tan et al.   Nature Chemistry

Organic Photoredox-Catalyzed Silyl Radical Generation from Silylboronate

(2022) Naho Takemura et al.   ACS Catalysis

Copper‐Photocatalyzed Hydrosilylation of Alkynes and Alkenes under Continuous Flow

(2021) Mingbing Zhong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Conjugated Polymers Inspired by Crystalline Silicon

(2019) Eric A. Marro et al.   CHEMISTRY OF MATERIALS

Progress in the Chemistry of Tetrahydroquinolines

(2019) Isravel Muthukrishnan et al.   CHEMICAL REVIEWS

Pyridine‐Based Organocatalysts for Regioselective syn ‐1,2‐Silaboration of Terminal Alkynes and Allenes

(2019) Yohei Morimasa et al.   Asian Journal of Organic Chemistry

Quadruple Borylation of Terminal Alkynes

(2019) Daiki Yukimori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Double Hydroboration of Quinolines via Borane Catalysis: Diastereoselective One Pot Synthesis of 3‐Hydroxytetrahydroquinolines

(2019) Eunae Kim et al.   ADVANCED SYNTHESIS & CATALYSIS

Boron in drug design: Recent advances in the development of new therapeutic agents

(2019) Guilherme Felipe Santos Fernandes et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Polar organometallic strategies for regioselective C–H metallation of N-heterocyclic carbenes

(2018) Marina Uzelac et al.   CHEMICAL COMMUNICATIONS

Ni-catalyzed hydroboration and hydrosilylation of olefins with diboron and silylborane

(2018) Toshiyuki Kamei et al.   TETRAHEDRON LETTERS

Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

(2018) Jennifer V. Obligacion et al.   Nature Reviews Chemistry

Recent advances in chemical dearomatization of nonactivated arenes

(2018) William C. Wertjes et al.   CHEMICAL SOCIETY REVIEWS

Quest for Novel Chemical Entities through Incorporation of Silicon in Drug Scaffolds

(2017) Remya Ramesh et al.   JOURNAL OF MEDICINAL CHEMISTRY

Fifty Years of Hydrosilylation in Polymer Science: A Review of Current Trends of Low-Cost Transition-Metal and Metal-Free Catalysts, Non-Thermally Triggered Hydrosilylation Reactions, and Industrial Applications

(2017) Robin Hofmann et al.   Polymers

Ultrapure Blue Thermally Activated Delayed Fluorescence Molecules: Efficient HOMO-LUMO Separation by the Multiple Resonance Effect

(2016) Takuji Hatakeyama et al.   ADVANCED MATERIALS

Synthesis of Enantiomerically Enriched Chiral Tetrahydroquinolines via Sequential Dearomatization/Enantioselective Borylation Reactions

(2016) Koji Kubota et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Synthesis of Chiral Piperidines via the Stepwise Dearomatization/Borylation of Pyridines

(2016) Koji Kubota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Transition-Metal-Catalyzed Synthetic Transformations of Organosilicon Reagents

(2016) Takeshi Komiyama et al.   ACS Catalysis

Catalytic Silylation of Unactivated C–H Bonds

(2015) Chen Cheng et al.   CHEMICAL REVIEWS

Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds

(2015) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aggregation-induced emission of siloles

(2015) Zujin Zhao et al.   Chemical Science

Transition-Metal-Free BF3-Mediated Oxidative and Non-Oxidative Cross-Coupling of Pyridines

(2014) Quan Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron-Catalyzed Silylative Reduction of Quinolines: Selective sp3 C–Si Bond Formation

(2014) Narasimhulu Gandhamsetty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Combinations for Dehalogenative Metalation Involving Organic Compounds

(2013) David Tilly et al.   CHEMICAL REVIEWS

Transition-Metal-Free BF3-Mediated Regioselective Direct Alkylation and Arylation of Functionalized Pyridines Using Grignard or Organozinc Reagents

(2013) Quan Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of Organotrifluoroborate Salts: Precipitation-Driven Equilibrium under Non-Etching Conditions

(2012) Alastair J. J. Lennox et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes

(2012) Hajime Ito et al.   CHEMICAL COMMUNICATIONS

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Boron Containing Compounds as Protease Inhibitors

(2012) Reem Smoum et al.   CHEMICAL REVIEWS

Trivalent boron nucleophile as a new tool in organic synthesis: reactivity and asymmetric induction

(2012) Jessica Cid et al.   CHEMICAL SOCIETY REVIEWS

Organosilicon Molecules with Medicinal Applications

(2012) Annaliese K. Franz et al.   JOURNAL OF MEDICINAL CHEMISTRY

Polycyclic π-Electron System with Boron at Its Center

(2012) Shohei Saito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Advances in the Chemistry of Tetrahydroquinolines

(2011) Vellaisamy Sridharan et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines

(2011) Kazuyuki Oshima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Catalytic C–Si Bond Formation in an Aqueous Medium. Enantioselective NHC-Catalyzed Silyl Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2011) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS