Metallomimetic Chemistry of a Cationic, Geometrically Constrained Phosphine in the Catalytic Hydrodefluorination and Amination of Ar–F Bonds

Calix[4]pyrrolato Stannate(II): A Tetraamido Tin(II) Dianion and Strong Metal‐Centered σ‐Donor

(2022) Heiko Ruppert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bismuth Redox Catalysis: An Emerging Main-Group Platform for Organic Synthesis

(2022) Hye Won Moon et al.   ACS Catalysis

Dual Reactivity of a Geometrically Constrained Phosphenium Cation

(2022) Solomon Volodarsky et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand‐Enabled Disproportionation of 1,2‐Diphenylhydrazine at a P V ‐Center**

(2022) Simon B. H. Karnbrock et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mesomeric Tuning at Planar Bi centres: Unexpected Dimerization and Benzyl C−H Activation in [ CN 2 ]Bi Complexes

(2022) Toren Hynes et al.   ChemPlusChem

A Multidimensional Approach to Carbodiphosphorane–Bismuth Coordination Chemistry: Cationization, Redox-Flexibility, and Stabilization of a Crystalline Bismuth Hydridoborate

(2022) Akachukwu D. Obi et al.   Inorganic Chemistry

Main Group Redox Catalysis of Organopnictogens: Vertical Periodic Trends and Emerging Opportunities in Group 15

(2021) Jeffrey M. Lipshultz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphorus-Based Catalysis

(2021) Changmin Xie et al.   ACS Central Science

Catalytic Hydrodefluorination via Oxidative Addition, Ligand Metathesis, and Reductive Elimination at Bi(I)/Bi(III) Centers

(2021) Yue Pang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An isolable, crystalline complex of square-planar silicon(IV)

(2021) Fabian Ebner et al.   Chem

The inversion of tetrahedral p-block element compounds: general trends and the relation to the second-order Jahn–Teller effect

(2021) Lukas M. Sigmund et al.   Chemical Science

Dihalides of Sterically Constrained Tricyclic Phosphines, Lewis Acidity and Fluoride Affinity, Chloride Abstraction, and a Phosphonium Cation, Dimethylphosphorane

(2020) Alexander Brand et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Front Cover: Unusual Energetic Periodate, Sulfate and Amino-bistetrazolate Salts of the Trinitropropylammonium Cation (Z. Anorg. Allg. Chem. 1/2020)

(2020) Cornelia C. Unger et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Element-Ligand Cooperativity with p-Block Elements

(2020) Lutz Greb et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Pincer‐Type Ligand‐Assisted Catalysis and Small‐Molecule Activation by non‐VSEPR Main‐Group Compounds

(2020) Subrata Kundu   Chemistry-An Asian Journal

Round-Trip Oxidative Addition, Ligand Metathesis, and Reductive Elimination in a PIII/PV Synthetic Cycle

(2020) Soohyun Lim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Di-ortho-beryllated Carbodiphosphorane: A Compound with a Metal–Carbon Double Bond to an Element of the s-Block

(2020) Magnus R. Buchner et al.   ORGANOMETALLICS

A Redox-Confused Bismuth(I/III) Triamide with a T-Shaped Planar Ground State

(2019) Marcus B. Kindervater et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pushing the Lewis Acidity Boundaries of Boron Compounds With Non-Planar Triarylboranes Derived from Triptycenes

(2019) Ali Ben Saida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Periodicity in Structure, Bonding, and Reactivity for p‐Block Complexes of a Geometry Constraining Triamide Ligand

(2019) Katherine M. Marczenko et al.   CHEMISTRY-A EUROPEAN JOURNAL

Calix[4]pyrrole Aluminate: A Planar Tetracoordinate Aluminum(III) Anion and Its Unusual Lewis Acidity

(2019) Fabian Ebner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ambiphilic geometrically constrained phosphenium cation

(2018) Solomon Volodarsky et al.   CHEMICAL COMMUNICATIONS

Catalytic Hydrodefluorination of C−F Bonds by an Air-Stable PIII Lewis Acid

(2018) Saurabh S. Chitnis et al.   CHEMISTRY-A EUROPEAN JOURNAL

P–N Cooperative Borane Activation and Catalytic Hydroboration by a Distorted Phosphorous Triamide Platform

(2017) Yi-Chun Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity Studies on a Diazadiphosphapentalene

(2016) Jingjing Cui et al.   CHEMISTRY-A EUROPEAN JOURNAL

On the Catalytic Hydrodefluorination of Fluoroaromatics Using Nickel Complexes: The True Role of the Phosphine

(2014) Alma Arévalo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free σ-Bond Metathesis in Ammonia Activation by a Diazadiphosphapentalene

(2014) Jingjing Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular N–H Oxidative Addition of Ammonia, Alkylamines, and Arylamines to a Planar σ3-Phosphorus Compound via an Entropy-Controlled Electrophilic Mechanism

(2014) Sean M. McCarthy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main Group Redox Catalysis: Reversible PIII/PV Redox Cycling at a Phosphorus Platform

(2012) Nicole L. Dunn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY