Development of Selective Molecular Transformations Based on Unique Chemical Properties of Silver Catalyst: A Theoretical Analysis and Experimental Verification

Chemical Equivalent of Arene Monooxygenases: Dearomative Synthesis of Arene Oxides and Oxepines

(2020) Zohaib Siddiqi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed, Chemo- and Enantioselective Intramolecular Dearomatization of Indoles to Access Sterically Congested Azaspiro Frameworks

(2020) Jun Ueda et al.   JOURNAL OF ORGANIC CHEMISTRY

Shaping Molecular Landscapes: Recent Advances, Opportunities, and Challenges in Dearomatization

(2020) Christopher J. Huck et al.   Chem

Atypical Dearomative Spirocyclization of β-Naphthols with Diazoacetamides Using a Silver Catalyst

(2020) Haruka Homma et al.   ORGANIC LETTERS

Asymmetric Intramolecular Dearomatization of Nonactivated Arenes with Ynamides for Rapid Assembly of Fused Ring System under Silver Catalysis

(2020) Tsubasa Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploring New Reactivity of Metal Carbenoids and its Application to Organic Synthesis

(2019) Masato Kono et al.   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

Silver‐Catalyzed Asymmetric Insertion into Phenolic O–H Bonds using Aryl Diazoacetates and Theoretical Mechanistic Studies

(2019) Shingo Harada et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Formal Synthesis of (+)-Catharanthine via Desymmetrization of Isoquinuclidine

(2019) Masato Kono et al.   ORGANIC LETTERS

Palladium-Catalyzed Oxygenative Cross-Coupling of Ynamides and Benzyl Bromides by Carbene Migratory Insertion

(2018) Yunpeng Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Key mechanistic insights into the intramolecular C-H bond amination and double bond aziridination in sulfamate esters catalyzed by dirhodium tetracarboxylate complexes

(2018) Adrián Varela-Álvarez et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Binary additive effect of benzoic acid in ipso -Friedel-Crafts-type dearomatization of phenols using a chiral silver phosphate

(2018) Hiroki Nakayama et al.   TETRAHEDRON

Recent advances in chemical dearomatization of nonactivated arenes

(2018) William C. Wertjes et al.   CHEMICAL SOCIETY REVIEWS

Donor Rhodium Carbenes by Retro-Buchner Reaction

(2018) Mauro Mato et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inverting Steric Effects: Using “Attractive” Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer

(2017) Minxue Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of (+)-Pancratistatins via Catalytic Desymmetrization of Benzene

(2017) Lucas W. Hernandez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective Asymmetric Intramolecular Dearomatization of Phenols with α-Diazoacetamides Catalyzed by Silver Phosphate

(2017) Hiroki Nakayama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Chemoselective α-Amination of Acylpyrazoles: A Concise Route to Unnatural α-Amino Acid Derivatives

(2016) Keisuke Tokumasu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dearomative dihydroxylation with arenophiles

(2016) Emma H. Southgate et al.   Nature Chemistry

Synthesis of Spirocyclic and Fused Cyclic Compounds by Transition-Metal-Catalyzed Intramolecular Friedel–Crafts-Type Reactions of Phenol Derivatives

(2016) Tetsuhiro Nemoto et al.   SYNLETT

Origins of unique gold-catalysed chemo- and site-selective C–H functionalization of phenols with diazo compounds

(2016) Yuan Liu et al.   Chemical Science

Zinc-Catalyzed Alkyne Oxidation/CH Functionalization: Highly Site-Selective Synthesis of Versatile Isoquinolones and β-Carbolines

(2015) Long Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General Approach to Nitrogen-Bridged Bicyclic Frameworks by Rh-Catalyzed Formal Carbenoid Insertion into an Amide C–N Bond

(2015) Shingo Harada et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Spirocyclic or Fused Cyclic Compounds Using Transition Metal-Catalyzed Dearomatization of Phenols

(2015) Tetsuhiro Nemoto et al.   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

Enantioselective Palladium-Catalyzed Insertion of α-Aryl-α-diazoacetates into the OH Bonds of Phenols

(2014) Xiu-Lan Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of Indoles by Copper-Mediated Carbene Transfer

(2014) Manuela Delgado-Rebollo et al.   ChemCatChem

Reaction of Alkynes and Azides: Not Triazoles Through Copper-Acetylides but Oxazoles Through Copper-Nitrene Intermediates

(2014) Estela Haldón et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Syntheses of (−)-Kopsifoline D and (−)-Deoxoapodine: Divergent Total Synthesis via Late-Stage Key Strategic Bond Formation

(2014) Kiyoun Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Aspeverin via an Iodine(III)-Mediated Oxidative Cyclization

(2014) Adam M. Levinson   ORGANIC LETTERS

Direct Stereospecific Synthesis of Unprotected N-H and N-Me Aziridines from Olefins

(2014) Jawahar L. Jat et al.   SCIENCE

Palladium-Catalyzed Intramolecularipso-Friedel-Crafts Alkylation of Phenols and Indoles: Rearomatization-Assisted Oxidative Addition

(2013) Tetsuhiro Nemoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper-Catalyzed Intramolecular Phenolic OH Bond Insertion: Synthesis of Chiral 2-Carboxy Dihydrobenzofurans, Dihydrobenzopyrans, and Tetrahydrobenzooxepines

(2013) Xiao-Guang Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tunable, Chemoselective Amination via Silver Catalysis

(2013) Jared W. Rigoli et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation of Rhodium(I) Carbenes from Ynamides and Their Reactions with Alkynes and Alkenes

(2013) Renhe Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

(2012) Jennifer L. Roizen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rh2(S-biTISP)2-Catalyzed Asymmetric Functionalization of Indoles and Pyrroles with Vinylcarbenoids

(2012) Yajing Lian et al.   ORGANIC LETTERS

Iron-Catalyzed CH Fuctionalization of Indoles

(2011) Yan Cai et al.   ADVANCED SYNTHESIS & CATALYSIS

Phosphate ligands in the gold(i)-catalysed activation of enynes

(2011) Mihai Raducan et al.   CHEMICAL COMMUNICATIONS

Rhodium(II)-Catalyzed Enantioselective C−H Functionalization of Indoles

(2011) Andrew DeAngelis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Carbenoid Insertion into Phenolic O–H Bonds with a Chiral Copper(I) Imidazoindolephosphine Complex

(2011) Takao Osako et al.   ORGANIC LETTERS

Rhodium-Catalyzed C–H Amination. An Enabling Method for Chemical Synthesis

(2011) J. Du Bois   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Silver-Catalyzed C-C Bond Formation Between Methane and Ethyl Diazoacetate in Supercritical CO2

(2011) A. Caballero et al.   SCIENCE

Site-specific introduction of gold-carbenoids by intermolecular oxidation of ynamides or ynol ethers

(2010) Paul W. Davies et al.   CHEMICAL COMMUNICATIONS

Enantioselective Copper-Catalyzed Intramolecular O−H Insertion: An Efficient Approach to Chiral 2-Carboxy Cyclic Ethers

(2010) Shou-Fei Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Novel Method for Synthesizing Spiro[4.5]cyclohexadienones through a Pd-Catalyzed Intramolecularipso-Friedel−Crafts Allylic Alkylation of Phenols

(2010) Tetsuhiro Nemoto et al.   ORGANIC LETTERS

Silver-Mediated Synthesis of Heterocycles

(2008) Míriam Álvarez-Corral et al.   CHEMICAL REVIEWS

Ag-Mediated Reactions: Coupling and Heterocyclization Reactions

(2008) Jean-Marc Weibel et al.   CHEMICAL REVIEWS

Catalytic Reaction of Aryldiazoacetates with Indole and Its Derivatives:Profound Effect of N-1 Substitutent on the Reaction Pathways

(2008) Xue-Jing ZHANG et al.   CHINESE JOURNAL OF CHEMISTRY

Catalytic Asymmetric Reaction with Water: Enantioselective Synthesis of α-Hydroxyesters by a Copper–Carbenoid OH Insertion Reaction

(2007) Shou-Fei Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions of macrocyclic rhodium carbenoids: regioselective synthesis of indol-3-yl macrocyclic lactones and cryptands

(2007) Sengodagounder Muthusamy et al.   TETRAHEDRON LETTERS