Metal-Ligand Cooperative Bond Cleavage/Formation and Their Catalytic Applications with Cyclopentadienone Metal Complexes

Heterolytic Oxidative Addition of sp2 and sp3 C–H Bonds by Metal–Ligand Cooperation with an Electron-Deficient Cyclopentadienone Iridium Complex

(2021) Takuya Higashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A tautomeric ligand enables directed C‒H hydroxylation with molecular oxygen

(2021) Zhen Li et al.   SCIENCE

Bifunctional beginnings

(2021) Rosie J. Somerville   Nature Reviews Chemistry

Cleavage of C–C and C–O bonds in β-O-4 Linkage of Lignin Model Compound by Cyclopentadienone Group 8 and 9 Metals Complexes

(2020) Shuhei Kusumoto et al.   CHEMISTRY LETTERS

Umpolung of B−H Bonds by Metal–Ligand Cooperation with Cyclopentadienone Iridium Complexes

(2020) Takuya Higashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal–Ligand Cooperative C–H Bond Formation by Cyclopentadienone Platinum Complexes

(2019) Takuya Higashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cleavage of Si–H, B–H, and C–H Bonds by Metal–Ligand Cooperation

(2019) Takuya Higashi et al.   CHEMICAL REVIEWS

Transfer Hydrogenation of Aldehydes, Allylic Alcohols, Ketones, and Imines Using Molybdenum Cyclopentadienone Complexes

(2018) Weiwei Wu et al.   ORGANOMETALLICS

[2,2′-Bipyridin]-6(1H)-one, a Truly Cooperating Ligand in the Palladium-Mediated C–H Activation Step: Experimental Evidence in the Direct C-3 Arylation of Pyridine

(2018) Vanesa Salamanca et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

E–H (E = B, Si, Ge) bond activation of pinacolborane, silanes, and germanes by nucleophilic palladium carbene complexes

(2016) Cezar C. Comanescu et al.   CHEMICAL COMMUNICATIONS

The Retro-Hydroformylation Reaction

(2015) Shuhei Kusumoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Ligand Cooperation

(2015) Julia R. Khusnutdinova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H Activation Reactions of a Nucleophilic Palladium Carbene

(2015) Cezar C. Comanescu et al.   ORGANOMETALLICS

Direct and selective hydrogenolysis of arenols and aryl methyl ethers

(2015) Shuhei Kusumoto et al.   Nature Communications

Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane

(2013) Timo Stahl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Acceptorless Dehydrogenation of C–C Single Bonds Adjacent to Functional Groups by Metal–Ligand Cooperation

(2013) Shuhei Kusumoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bifunctional Rhenium Complexes for the Catalytic Transfer-Hydrogenation Reactions of Ketones and Imines

(2012) Anne Landwehr et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Dearomatized Anionic PNP Pincer Rhodium Complex: C–H and H–H Bond Activation by Metal–Ligand Cooperation and Inhibition by Dinitrogen

(2011) Leonid Schwartsburd et al.   ORGANOMETALLICS

Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst

(2010) Brian L. Conley et al.   CHEMICAL REVIEWS

Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism

(2010) Keary M. Engle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of an Iridium(I) Acetonyl PNP Complex. Experimental and Computational Study of Metal−Ligand Cooperation in H−H and C−H Bond Activation via Reversible Ligand Dearomatization

(2010) Leonid Schwartsburd et al.   ORGANOMETALLICS

A Boron-Substituted Analogue of the Shvo Hydrogenation Catalyst: Catalytic Hydroboration of Aldehydes, Imines, and Ketones

(2009) Liza Koren-Selfridge et al.   ORGANOMETALLICS

Imidazol-2-yl Complexes of Cp*Ir as Bifunctional Ambident Reactants

(2008) Valentín Miranda-Soto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY