Bimodal substitution behavior in the reaction of N,N’-diisopropylformamidine with [Os3(CO)10(NCMe)2]: kinetics and molecular structures of the formamidinate-substituted clusters HOs3(CO)9[μ-C(O)NPr C(H)NPr ], HOs3(CO)10[μ-NPr C(H)NPr ], and HOs3(CO)9[μ3-NPr C(H)NPr ]

Title
Bimodal substitution behavior in the reaction of N,N’-diisopropylformamidine with [Os3(CO)10(NCMe)2]: kinetics and molecular structures of the formamidinate-substituted clusters HOs3(CO)9[μ-C(O)NPr C(H)NPr ], HOs3(CO)10[μ-NPr C(H)NPr ], and HOs3(CO)9[μ3-NPr C(H)NPr ]
Authors
Keywords
Osmium clusters, Formamidinate ligand, Kinetic modeling, X-ray structures, DFT
Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume -, Issue -, Pages 121709
Publisher
Elsevier BV
Online
2021-01-19
DOI
10.1016/j.jorganchem.2021.121709

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