Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 8, Issue 7, Pages 1133-1135Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201900303
Keywords
N-heterocyclic carbene; palladium catalyst; synergistic catalysis; acylation; ketone
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Funding
- JSPS KAKENHI [JP18H01971, JP17H06449]
- Kanazawa University SAKIGAKE project 2018
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A synergistic action of a thiazolium N-heterocyclic carbene catalyst and a palladium-bisphosphine catalyst has enabled the allylation between aldehydes acyl anions and allylic amines to afford beta,gamma-unsaturated ketones, which are versatile synthetic intermediates for organic synthesis.
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